汪继强 动力锂离子电池及其关键材料开发和评估.ppt

Tianjin Institute of Power Sources Development and Evaluation of Power Li-ion Battery and Key Materials 动力锂离子电池及其关键材料开发与评估 Xingjiang LIU, Chengwei XIAO and Jiqiang WANG National Key Lab. of Power Sources, China Tianjin Institute of Power Sources, Tianjin 300381, China The 4th International Forum on Power LIB for EV , Oct. 17, 2009, Beijing Outline Introduction Development target and status of Power LIB Key materials for power LIB Technical issues and solution Summary Introduction National program for next generation power battery USA: 2.4B$, 48 Projects, for Next-Generation of Batteries and Electric Vehicles Japan: 0.2B$, 42 subjects including Batteries for Stationary Vehicle China: “13 cities, 1000 EVs” plan, “863”projects, “973” projects Type Lead-acid Ni-MH LIB EC Specific Energy（Wh/kg） 20-40 50-80 80-140 2-6 Specific Power（W/kg） 1000 1000 1000 1000 Cycle life（100%DOD） 500 1000 500-1000 100000 Self discharge Fast Slow Very slow Fast Safety Excellent Good Acceptable Excellent Cost Very Low Low High High Introduction Table Comparison of electrochemical power sources Technical requirement guidance (second stage) for power battery in eleventh five-year plan Capacity（Ah） 8、20 50 100 Power density（W/kg） ≥1800 ≥700 ≥500 Energy density（Wh/kg） LiFePO4 ≥65 ≥110 ≥110 LiMn2O4 ≥70 ≥120 ≥120 Max. discharge rate 30C(20s) 6C(30s) 5C(30s) Max. charge rate 10C(10s) (60s) 4C(60s) Internal resistance（mΩ） ≤2.0 ≤3.0 ≤2.5 Safety Pass requirements of industiral norm or national standard Pack cycle life（10,000km） 15（LFP），10（LMO） Cost (RMB Yuan/Wh） ≤3 ≤2 ≤2 Performance of Li-ion battery for EV Manufacturer Positive material Negative material Specific energy (Wh/kg) Power density (W/kg) Capacity (Ah) A LiFePO4 MCMB 92 482 40 B LiFePO4 MCMB 107 663 11.5 C LiFePO4 MCMB 77 590 40 D LiFePO4 MCMB 92 439 60 E LiMn2O4 MCMB 112 487 100 Key Materials Cathode: LiMn2O4, LFP, NCM, LVP Anode: NGR, HC, LTO Electrolyte: LiPF6 based, LiBOB, ion liquid Separator: PE, PP, PP/PE/PP Key Materials-Li