Eu3+掺杂钛酸盐红色LED材料.docxVIP

PAGE I Eu3+掺杂钛酸盐红色LED材料 【摘要】：白色发光二极管被誉为第四代照明光源，由于它具有使用寿命长、节能环保、显色效果好以及污染较小的特点，是一种新型的固态照明光源，近年来备受科研人员的广泛关注。现阶段较为普遍制作白光LED的方法是蓝色LED芯片激发黄色荧光粉，但是这种方法缺少了一定的红色成分，使得其显色指数和色温等光学性能参数不太理想。因此，寻找能够与白光LED相匹配的红色荧光粉显得尤为重要。本次毕业设计通过高温固相法合成制作得到NaY1-xTiO4：xEu3+荧光粉，同时本论文也详细探究了样品的发光性能。在615nm发射波长监控下，该发光材料的激发峰位置处于362nm、383 nm、396 nm、409 nm以及 465 nm处，其分别对应7F0→5D4、7F0→5G2、7F0→5L6、7F0→5D3和7F0→5D2跃迁。该发光材料在受到396nm波长辐照时，掺杂不同浓度Eu3+样品都有3个明显发射峰，其位置位于590nm、615nm和702nm处。通过XRD衍射仪测试掺杂入各种Eu3+浓度的发光材料的物相结构，发现掺入不同Eu3+浓度后没有改变基质的晶体结构。通过测量Eu3+浓度与发光强度的关系，可知，当Eu3+掺杂的量增加时，荧光材料的发光强度是先变强后变弱，掺入浓度为10％时样品的发光强度最大。经研究表明NaYTiO4：Eu3+系列发光材料与LED芯片匹配，其在白光LED中的应用很有研究价值。 【关键词】：铕离子，钛酸盐，高温固相法，发光材料  Eu3+-doped red titanatematerials for LED Abstract：White light-emitting diode is known as the fourth-generation lighting source. Because of its long service life, energy saving and environmental protection, good color rendering effect and low pollution, it is a new type of solid-state lighting source, which has been widely used by researchers in recent years. At present, the method for making white LEDs is more common. The blue LED chip excites the yellow phosphor, but this method lacks a certain red component, which makes the optical performance parameters such as color rendering index and color temperature less than ideal. Therefore, it is particularly important to find red phosphors that match the white LEDs. The graduation design was synthesized by high temperature solid phase method to obtain NaY1-xTiO4:xEu3+ phosphor. At the same time, the luminescence properties of the sample were also studied in detail. Under the monitoring of the emission wavelength of 615 nm, the excitation peak positions of the luminescent materials are at 362 nm, 383 nm, 396 nm, 409 nm and 465 nm, which correspond to 7F0→5D4, 7F0→5G2, 7F0→5L6, 7F0→5D3 and 7F0 → 5D2 transition. When irradiated by 396nm wavelength, the luminescent material has three distinct emission peaks with different concentrations of Eu3+, and its positions are located at 590nm, 615