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laParticle size analysis-Laser diffraction methods
(ISO-13320-1)
Introduction
Laser diffraction methods are nowadays widely used for particle
sizing in many different applications. The success of the technique is
based on the tact that it can be applied to various kinds of particulate
systems, is fast and can be automated and that a variety of commercial
instruments is available. Nevertheless, the proper use of the instrument
and the interpretation of the results require the necessary caution.
Therefore, there is a need for establishing an international standard
for particle size analysis by laser diffraction methods. Its purpose is to
provide a methodology for adequate quality control in particle size
analysis.
Historically, the laser diffraction technique started by taking only
scattering at small angles into consideration and, thus, has been known by
the following names:
- fraunhofer diffraction;
- (near-) forward light scattering;
- low-angle laser light scattering (LALLS).
However, the technique has been broadened to include light
scattering in a wider angular range and application of the Mie theory in
addition to approximating theories such as Fraunhofer and anomalous
diffraction.
The laser diffraction technique is based on the phenomenon that
particles scatter light in all directions with an intensity pattern that is
dependent on particle size. All present instruments assume a spherical
shape for the particle. Figure 1 illustrates the characteristics of single
particle scattering patterns: alternation of high and low intensities, with
patterns that extend for smaller particles to wider angles than for larger
particles[2-7,10,15 in the bibliography].
Within certain limits the scattering pattern of an ensemble of
particles is identical to the sum of the individual scattering patterns of all
particles present. By using an
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