scr反应中nox吸附的原位红外数据分析总结.docx

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scr反应中nox吸附的原位红外数据分析总结.docx

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3482 1574, 1277, 1246 1485 1328 1619 1580, 1246 1279 1538 MnOx. AlzOs 1685, 1459,1398 3400-3600 1231 1320 1579 1603 (负值)， accompanied by significantly decreased IR- absorption at 1180- 1200 cm4 1533 1466 Ceo62Zro3sOz 1470-1375 1206-1065 1315-12651350-1250 1650-1375 1530-1480, 1290- 1250 1585-1500, 1300- 1260 1650-1600, 1225- 1170 1027 groups H-bonded hydroxyls nitrate species monodentate nitrate bridge NO 亍 species weakly absorbed no2 monodentate nitrate bridge mtrate bidentate nitrate NH： ions formed due to the H：O production of the SCR reaction W. S. Kijlstra. et al. J. Catal. 171(1997)219- 230. H2O bridged nitrites monodentate nitrites bidentate nitrates coordinated NH3 at Mil3* sites NH： species lmear NH； mtrites mtrito monodentate species (vN=O) M. Adamowska. et al. Catal. Today 137(2008)288-291. mtrito monodentate species (vN-O) nitrito bidentate(\-5) mtrito bidentate(\as) nitro compounds(v$) nitro compoimds(vQ nitrates monodentates nitrates bidentates nitrates bridgmg chelating nitrate 1240 1528 CO3O4, Mno.05coo.950x 1273 1293, 1319 144 1471 1544 1614 1238 1280 a broad band centered at 1489 1550 1618 NlnOx, Sm-NfnOx 1624 1442 1033 1542, 1309、1296 1212 1559 1201 1286 1296, 1539 1636 1038 1434 CeaTabOx 1242, 1601 1436 1459 1532 1576 1621 1455 NIiiOxTiOz 1581, 1541 1603, 1244, 1630 1522, 1276 3683（负值）,3870 （负值） 3600-3000 bidentate nitrate monodentate nitrate monodentate nitrites H. Hu, et al. J. Phys. Chem. C, 119(2015) 22924-22933 Nitro compound linear nitrites bidentate nitrates gaseous NO2 bridged nitrates monodentate nitrites linear nitrites bidentate nitrates gaseous NO2 bridged nitrate D. Meiig, et al.5 ACS Catal. 5(2015)5973- 5983 ionic nitrate monodentate nitrate bidentate nitrate bridged nitrite bidentate nitrate bridged nitrite bidentate nitrate bidentate nitrate bridged nitrate monodentate nitrate ionic nitrate bridging nitrate T. Zhang et al., Appl. Catal. B: Environ. 176-177 (2015)338- 346 m-no2 nitro compounds monodentate nitrite monoden