电分析法同时快速测定植物油中TBHQBHA和BHT研究.docxVIP

电分析法同时快速测定植物油中TBHQBHA和BHT研究 电分析法同时快速测定植物油中TBHQBHA和BHT研究 电分析法同时快速测定植物油中TBHQBHA和BHT研究 电剖析法同时迅速测定植物油中 TBHQ 、BHA 和 BHT 的研究 王佳蕊，郝雅茹，李书国 （河北科技大学生工学院 石家庄 050018） 纲要：本文主要研究了抗氧化剂 TBHQ 、BHA 和 BHT 在玻碳电极上的伏安性质，三者的循环伏安图表示： 3 个峰形优秀的氧化峰分别对应： TBHQ 的氧化峰电位为 590 mV ，BHA 的氧化峰电位为 710 mV ，BHT 的氧化峰电位为 1050 mV ，只有一个复原峰，电位为－ 90 mV 。经过试验优化了电剖析法测定植物油样抗氧 化剂的剖析技术参数。借助最小偏二乘法（ PLS），利用电化学剖析法展望了人工模拟试样中的 3 种抗氧 化剂的含量，展望结果及加标回收率是令人满意的。利用所开发的方法测定了实质油样中的抗氧化剂的含 量，其回收率在 94～ 104.1%，结果表示该法同时测定植物油中两种及以上的抗氧化剂是可行的，并且无需 提取、分别及冲洗等预办理程序，应用潜力巨大。 重点词：植物油，抗氧化剂，伏安法，化学计量学 中图分类号： 文件表记码： A 文章编号： 1003-0174 Rapid Determination of Three Synthetic Antioxidants: TBHQ 、 BHA and BHT in Vegetable Oils Electroanalytical Method Wang Jiarui，Hao Yaru, Li Shuguo* (College of Biosecience Bioengineering, Hebei University of Science and technology, Shijiazhuang, 050018) Abstract The voltammetric behavior of tert-butylhydroquinone (TBHQ), tert-butylhydroxytoluene (BHT), tert-butylhydroxyaniso e (BHA) at a glassy carbon electrode in acidic ethanol-1,2dichloroethane medium has been investigated. Cyclic voltammogram of these three compounds exhibited three well-defined oxidation waves with peak potentials of 590 mV, 710 mV and 1050 mV for TBHQ, BHA and BHT respectively, only one cathodic peak at the potential of -90 mV. Sensitive response for three antioxidants was obtained by using the differential pulse voltammetric (DPV) technique at the optimal analytical conditions. With the aid of partial least squares regression (PLS), the method for the simultaneous determination of ternary mixture of these antioxidants has been developed based on their electrochemical oxidation. The proposed method was applied to the determination of these antioxidants in a set of predicted samples and six commercial vegetable oil samples with no pretreatment of sample. Satisfactory results were obtained. The present method is proved to have potential for the simultaneous determination of three or more antioxidants in vegetable oils. Keywords Vegetable oils; Ant