分析化学课件：第五章 络合反应与络合滴定.pptVIP

* 27’ * Does Color need as box? Color Difference or Colors differ * 30 * T: transition point 在转变点时，M是未与Y结合的浓度 * T: transition point 在转变点时，M是未与Y结合的浓度 * * This makes the indicator ? * Is red colored * 35‘ Olivine? Olive? Olive like or just green * 35‘ * 37 * * 37 * 35“ * 若考虑Bi的变色点在4.0，确实误差较大，但是实验中学生要求的0.3%是针对教师的数据，两者都存在一个系统误差，所以没关系。若想准确，只能用Bi标准溶液来标定。 * 39 * 41 * Might change How to do? To simply How? * Ions in Presence – consider Ions Present. LgK for interference metal ion is small enough not to be titrated, * 43 * 45 The ) at the end of first sentence looks lost * You might try to decide on caps or small letters for your slide titles. This way is the route I would use if you decide on caps, that is preparations and verbs start with small letters. You have often made “Are” * 2 EDTA can complex almost…What does MY stand for Put in ( ), the first time used, 4 If M shows color * 1 * 4 * 4 * There is that Y again * 6 * * How about Protonation? * 7 * 8 * 8 * 可以看出谁能用来滴定，谁不能 * 9’ * 9 * 9 * 可以看出谁能用来滴定，谁不能 * Why caps in the title. Just one on When could be enough, though not wrong * 15 * 15 * 16 * * Could define SP * Calculate – extra c * Small lettered “sp”s. Is “and sp” clear? * 28 Does the difference in font intensity purposeful? * Increases by 10 fold * 10 fold * Increase by 10 fold * 68 * 10 fold * 27’ * Route Titration of Pb2+ When Ca2+ is Present (1)Selective Titration: ?logK=18.0-10.7=7.36.0 Yes (2)pH Range: αY(H) =αY(Ca)=108.7 pHmin=4.0 (3)pHoptimal＝？(XO）the pH where Et is the lowest! logK(PbY?)= 9.3, (pPb)sp=5.7=(pPb)t, pHoptimal=4.3 pHmax=7.0 Example Selective Titration of Bi3+ and Pb2+ in Pb-Bi alloy logK(BiY)=27.9, logK(PbY)=18.0 ?logK=9.96 ?Y(Pb)＝1+10-2.0+18.0=1016.0 If log ?Y(H)＝ log ?Y(Pb) = 16.0， pH =1.4 Bi3+ will form hydroxo complex at this pH. In reality，titration of Bi3+ is conducted at pH1.0 log ?Y(H)＝18.3, log ?MY(H)＝1.7, logK?(BiY)=11.38.0 If indicator factor is considered (pMt=4.0), Et0.1%. How do w