铝合金用钎剂中粘结材料的研究.docVIP

铝合金用钎剂中粘结材料的研究 摘要：本论文采用红外光谱仪、核磁共振仪、色谱 -质谱仪对铝合金钎焊用NHM?X100?20UB热分解性 树脂,稀释剂进行了分析,同时进行不同的配比、通 过蔡恩杯测定其粘度以及在不同温度、不同时间下测 定钎剂挥发的重量，以探究热分解树脂的挥发性。仪 器分析结果表明：热分解树脂的主要成分为：十八烯 酰胺,十四烷酰胺,3-庚醇，丙烯酸类树脂。 稀释剂的主要成分为：1 ?甲氧基9甲基，丙二酸,二甲 氧基丁烷。实验结果表明：稀释剂的配比越高‘其粘 度随稀释剂的加入量的增加而减小，其涂布之后硬度 也较低,当稀释剂加入量为41.2%时，钎焊剂为最佳 配比。在测试其挥发性时,相同温度下，当热分解性 树脂的配比率一定时，稀释剂的配比率越高,其挥发 率就越大。7755 关键词：热分解树脂；粘度；挥发性；涂层强度 Research on bonding agent for aluminum brazing materials Abstract: This infrared spectroscopy, nuclear magnetic resonance, chromatography - mass spectrometry have been used to analyze composition of NHM-X100-20UB heat decomposable resin, diluent for aluminum alloy brazing. With a different ratio of all kinds of agent, the viscosityhave been measured by Zahn cup and at different temperatures at different times of volatile flux measured weight in order to explore the thermal decomposition of volatile resin. The results of instrumental analysis showed that: the main component of the thermal decomposition of the resin: eighteen amid巳 myristic acid amide 3 ? heptanol, an acrylic resin.The main components of the diluent: 1-methoxy-3 ? methyl malonic ^imethoxy-butane. The experimental results showed that: the higher the ratio of the diluent the viscosity with increase of the amount of diluent decreases, the hardness is low after coating, when the amount of diluent added was 41.2%, the brazing flux for the most good ratio. In the test the volatile, the same temperature, when the thermal decomposition of resin with the ratio constant, with the higher the ratio of diluent, the greater the cvaporation rate. 234钎剂组成对挥发性的影响11 2.3.4涂层强度11 2.4实验过程14 24.1配置钎焊剂13 242钎焊剂粘度的检测13 2.4.3钎焊剂挥发性的检测14 2.4.5钎焊剂涂层强度的检测15 3实验结果及讨论分析16 3.1产品组成剖析图谱16 3.2不同配比对钎焊剂粘度的影响23 33不同配比对钎焊剂挥发性的影响24 34钎焊剂涂布量的研究26 4结论27 致谢2 参考文献29 1前言 1.1铝合金钎焊 1.1.1铝合金钎焊概述 钱乙余、丁克俭等入口-2］研究发现钎焊是—种较为 有效的铝及其合金的精密焊接技术。钎焊是指用比母 材熔点低的金属材料作为钎料，用液态钎料润湿母材 和填充工件接口间隙并使其与母材相互扩散的焊接方 法。钎焊变形小，接头光滑美观,适合于焊接精密、 复杂和由不同材料组成的构件，如蜂窝结构板、透平 叶片、硬质合金刀具和印刷电路板等。钎焊前对工件 必须进行细致加工和严格清洗,除去油污和过厚的氧 化膜，