有机化学期中考试前.pptxVIP

复旦大学环境科学与工程系; ; ; ;; 1. Bimolecular Nucleophilic Substitution;;;1. Rate-determining factors of SN2;1. Rate-determining factors of SN2;1. Rate-determining factors of SN2;强碱是好的亲核剂;极化强的是好的亲核剂;1. Rate-determining factors of SN2;1. Elimination reactions;1. Saytzeff rule of Elimination reactions;1. Stereoselectivity of Elimination reactions;1. Stereoselectivity of Elimination reactions;1. Steric selectivity of Elimination reactions;1. Steric selectivity of Elimination reactions; ;;Victor Grignard (1871 ~1935);;Victor Grignard (1871 ~1935);化合物;应用: 通过Grignard试剂制备氘代化合物或还原卤代烷至烷烃;; ;3.1 Structure of alcohols;3.1 Structure of alcohols;氧化反应;3.2 Nomenclature;3.2 Nomenclature;3.2 Nomenclature;3.3 Substitution;醇羟基的取代;;3.3 Substitution;;与氯化亚砜（SOCl2）的反应;;;3.3 Substitution;酸性;醇羟基中氢的反应; 2(CH3)3COH + 2K 2(CH3)3COK + H2;氧化反应;3.4 Oxidation;脱水反应;3.4 Elimination;3.4 Elimination;Conclusions-1;氧化反应; ; ;第五章 致谢;谢 谢！