自修复微胶囊的制备研究论文.docVIP

1绪论 [键入文字] 题目：自修复微胶囊的制备研究 PAGE 25 自修复微胶囊的制备研究 摘要 本文以脲醛树脂为壁材，以质量比为8:2的环氧丙烯酸树脂（EA）和活性稀释剂（TPGDA）混合物为芯材，采用原位聚合法制备了脲醛树脂包覆EA/TPGDA的微胶囊。通过探讨乳化剂用量、芯壁质量比、搅拌速率、反应温度、pH值和尿素与甲醛的质量比等反应参数对微胶囊性能的影响，确定了合成微胶囊的最佳工艺路线。同时，采用光学显微镜（OM）、傅里叶红外光谱仪（FTIR）等仪器对微胶囊的形态、结构进行了分析和表征。 实验结果表明，乳化剂的浓度为4%，嚢芯与囊壁质量比为1:0.6，搅拌速率为1500 r/min，反应温度为70℃，尿素甲醛质量比为1:2时所制备的微胶囊分散性较好，粒径分布均匀，产率比较高。 关键词：自修复；微胶囊；原位聚合 Preparation and Characterization of Microcapsules for Self - healing Material Abstract In this paper,urea-formaldehyde resin as wall material to mass ratio of 8:2 epoxy acrylate (EA) and reactive diluents (TPGDA) mixture as core material,the use of in situ polymerization of urea-formaldehyde resin prepared by coating a legitimate EA / TPGDA of microcapsules. By exploring emulsifier,core wall mass ratio,stirring rate,reaction temperature,pH and the mass ratio of urea and formaldehyde microcapsules reaction parameters such as performance,determine the optimal process route synthetic microcapsules. Meanwhile，the use of optical microscopy (OM),Fourier transform infrared spectroscopy (FTIR) and other equipment to form microcapsules structure were analyzed and characterized. Experimental results indicate that the concentrations of 4% emulsifier，cyst wall core mass ratio of 1:0.6 and the stirring rate of 1500 r / min,the reaction temperature was 70 ℃,the quality of the prepared urea-formaldehyde ratio of 1:2 microcapsule dispersion is preferably uniform size distribution,a relatively high yield. Key words: Self-healing; Macrocapsule; In-situ polymerization 目 录 TOC \o 1-3 \h \z \u 18971 1 绪论 1 30515 1.1 引言 1 20591 1.2 材料自修复 1 28452 1.2.1 材料自修复的概念 1 28665 1.2.2 材料自修复的方法 1 526 1.3 微胶囊 2 19396 1.3.1 微胶囊的概念 2 30132 1.3.2 芯材的选择 2 3552 1.3.3 壁材的选择 3 16853 1.3.4 微胶囊的释放方式 3 13625 1.3.5 微胶囊的应用 4 24369 1.4 自修复微胶囊机理 4 32523 1.5 自修复微胶囊的制备方法 5 1961 1.5.1 化学法制备微胶囊 5 12542 1.5.2 物理化学法 6 14434 1.5.3 物理法 7 28985 1.6 影响自修复效果的因素 8 3613 1.7 微胶囊表征方法 8 999 1.8 本文的研究背景、内容及意义 8 5401 1