荧光聚合物的制备及表征论文.docVIP

题目：荧光聚合物的制备及表征 PAGE I PAGE I 荧光聚合物的制备及表征 摘 要 聚乙烯亚胺(Polyethyleneimine PEI)，是一种水溶性的阳离高分子聚合物，它自身具有很好的水溶性、高附着性和吸附性，能够与不同的物质相结合。而且其自身含有能够发光的叔胺生色基团，但其荧光极易发生淬灭。 本论文利用柠檬酸来修饰聚乙烯亚胺，通过酰化反应制备出超支化聚合物来提高聚乙烯亚胺自身的荧光性能，确定其配比。通过H-NMR(核磁氢谱)、红外光谱、Zeta电位测试对PEI-CA合成聚合物进行了精细的结构表征。并对柠檬酸修饰的聚乙烯亚胺水溶液的紫外可见吸收光谱、荧光发射光谱以及量子产率进行了测定，研究其荧光性能。结果表明，聚合物结构中含有大量的酰胺键，Zeta电位为8.78mv，具有很好的水溶性和稳定性；且该荧光聚合物具有优异的荧光性能，激发波长的改变并不影响其最大发射波长，能够发出较强的蓝色荧光，其荧光量子产率为0.40。有望应用于细胞标记、发光二极管和光催化等领域。 关键词：聚乙烯亚胺；超支化聚合物；柠檬酸；荧光量子产率 PAGE II PAGE II Preparation and Characterization of Fluorescent Polymer Abstract Polyethyleneimine (Polyethyleneimine PEI), is a water-soluble cationic polymer, which itself has good water solubility, high adhesion and adsorption can be combined with different materials. And capable of emitting light of its own tertiary containing chromophore, but the fluorescence quenching prone. In this paper, the use of citric acid to modified polyethyleneimine, polyethyleneimine to improve their fluorescence properties of hyperbranched polymers by acylation reactions were prepared to determine its proportion. By H-NMR, infrared spectroscopy, Zeta potential test for PEI-CA synthetic polymers were characterized by fine. UV and aqueous solution of citric acid modified polyethylenimine visible absorption spectra, fluorescence quantum yield and emission spectra were measured to study the fluorescence properties. The results showed that the polymer structure contains a large amount of an amide bond, Zeta potential is 8.78mv,has good water solubility and stability; and the fluorescent polymer has excellent fluorescent properties, excitation wavelength does not affect its maximum emission wavelength can emit strong blue fluorescence, the fluorescence quantum yield of 0.40.Is expected to be applied to the field of cell markers, such as light-emitting diodes and photocatalysis. Key Words: polyethyleneimine; hyperbranched polymers; citrate; fluorescence quantum yield PAGE III PAGE III 目 录 TOC \o 1-3 \h \u