三种阳极改性提升微生物燃料电池产电性能.docVIP

PAGE PAGE 20 三种阳极改性提升微生物燃料电池产电性能 摘要：微生物燃料电池（MFCs）是一种利用微生物的催化作用，将废水中的劣质有机污染物作为化学能转化为电能的新型环境友好型可持续发展技术，具有显著的环境、经济效益。但是MFCs的低电子传出效率却始终限制该技术的实际扩大化应用。本文以改性电极表面性质为手段，探究了高温氮气环境下惰性热处理，高温空气环境下常态热处理，表面聚苯胺改性三种石墨阳极改性对MFCs输出效率的影响。扫描电子显微镜（SEM）结果显示改性的煅烧电极前后比表面积获得了极大的提升，聚苯胺表面则出现镂空框架结构。循环伏安测试（CV）,交流阻抗测试（EIS）对电极改性前后及微生物挂膜前后的电化学性能进行了分析，结果表面改性后的电极表面电子传递速率获得了极大的提升。对模拟MFCs反应器进行连续电流监测，其最大电流密度分别是未改性石墨电极的2.1倍、2.8倍、1.5倍的结果。这表明电极改性能有效提高MFCs的产电性能，为其应用提供了经验。 关键词：MFCs，惰性热处理，常态热处理，聚苯胺复合石墨 Three kinds of modified graphite anode enhance power output in microbial fuel cells (MFCs) Abstract: Sustainable societies require development of a new energy platform to generate enough power, while cut down on carbon emissions to balance the demands and the resources. Microbial fuel cells (MFCs) are a promising strategy for electricity production from a variety of materials, such as natural organic matter, complex organic waster or renewable biomass, and can be advantageously combined with application in wastewater treatment, with significant environmental and economic benefits. The electrode character is considered to be a key factor for triggering the applicable MFCs. Heat treatment under high temperature and nitrogen environment, heat treatment under high temperature and air environment and surface coated polyaniline (PANI) three modify ways in graphite substrate has been introduced in this paper. The structure and morphology of these anode materials were studied using scanning electron microscopy (SEM ). The electrochemical behavior of the composite catalysts was also investigated by means of cyclic vohammetry (CV)and electrochemical impedance spectroscopy(EIS)．Simulate the MFCs reactor and monitor the continuous current. The experiment results showed that，the maximum current density of modified electrodes were 2.1-, 2.8- or 1.5-fold more than unmodified electrode. The results demonstrate that one approach to increase rates of current density in MFCs is to modify anode materials to improve microbe-elec