Part_4分析和总结分析和总结.pdfVIP

New Way Chemistry for Hong Kong A-level Suggested Solutions for GCE Questions Part 4 Bonding and Structure (Book 1, p.330 – p.334) 36. (a) (i) Graphite Structure: Giant molecular layer structure with hexagonal arrays of carbon atoms arranged in layers. Within each layer, each carbon atom forms 3 covalent bonds with 3 other carbon atoms. Weak Van der Waal ’s forces hold the layers together. Hence graphite is soft and slippery as the weak attractions between the layers allow one layer of bonded atoms to slide over another. The non-bonding electrons of the carbon atoms in each layer are delocalised and free to move graphite is an electrical conductor. (ii) Iodine Structure: Simple molecular crystal lattice with I 2 molecules held in lattice sites by weak Van der Waal ’s forces (temporary dipole induced dipole forces).– I sublimes easily, as little energy is sufficient to separate the molecules. 2 I2 is a non-conductor of electricity as no mobile electrons or ions are present. (b) +107 + 496 + 79 + ( –328) + HLE = –574 HLE = –928 kJ/mol charge of cation charge of anion (c) L.E cation radius anion radius + + NaF and KCl have same cation charge and anion charge but radius of Na radius of K – – and radius