Part_5分析和总结分析和总结.pdfVIP

New Way Chemistry for Hong Kong A-level Suggested Solutions for GCE Questions Part 5 Chemical Kinetics (Book 2, p.82 – p.85) 23. (a) (b) Order w.r.t. NO = 2 2 2 Since rate (P ) , the graph of rate against (P ) is a straight line. NO NO (c) 1st order w.r.t O2 Gradient measures rate rate doubles when P doubles. O 2 2 (d) Rate = k(PNO ) (PO2) –2 –2 –1 Units for k: (N m ) s EA (e) In k = In A – RT EA 4 Gradient of graph = – = –2.95 10 R 4 EA = 2.95 10 8.31 J/mol = 245.1 kJ/mol doc 28 Manhattan Press (H.K.) Ltd. New Way Chemistry for Hong Kong A-level Suggested Solutions for GCE Questions 24. The order of a reaction is determined by the rate-determining step of the reaction. The decomposition of N O is not an elementary reaction but consists of a series of steps or 2 5 elementary reactions. The rate-determining step (slowest) involves the decomposition of 1 molecule of N O only 1st order w.r.t. N O . 2 5 2