Part_6分析和总结分析和总结.pdfVIP

New Way Chemistry for Hong Kong A-level Suggested Solutions for GCE Questions Part 6 Chemical Equilibria (Book 2, p.231 – p.239) 37. (a) A — Pt electrode 2+ 3 3+ 3 B — aq. Fe (1 mol/dm ) and aq. Fe (1 mol/dm ) C — voltmeter D — 1 atm. pressure 3+ 2+ (b) (i) The positive pole is electrode A : Fe /Fe half-cell. (ii) Electrons flow from the standard hydrogen electrode to electrode A. 3 (c) Increasing hydrogen ion concentration ( 1 mol/dm and lower pH) will shift hydrogen + – + equilibrium to LHS, i.e. more reduction occurs. H 2(g) 2H (aq) + 2e E (H /H 2) 0 V + Lower H 2 (g) pressure (i.e. 1 atm.) shifts hydrogen equilibrium to LHS E (H /H 2 ) 0 V (d) (i) Ecell = Eredn –Eox. = +0.77 – 0 = +0.77 V (ii) Voltage drops below +0.77 V. Potential difference across voltmeter decreases. 3+ 2+ + (e) 2Fe (aq) + H2 (g) 2Fe (aq) + 2H (aq) Reaction may not be kinetically feasible (too slow). Actual conditions may not be standard conditions. Prediction on feasibil