广州石化首创燃料氢检测新技术.pdfVIP

16 合成技术及应用 第37卷 [15]FigueiraCA.LopesPS.GomesCSB，etal.Neutral mono(5- molecular characterization tallics 625. aryl-2-iminopyrrolyl)nickel( Ⅱ)complexesas precatalysts for the synthesis of highly branched ethylene oligomers:preparation, Anilino anthracenequinone nickel catalyzed ethylene oligomerization and its heterogenezation Hu Haodong， CaiZhengguo (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Abstract: This paper is oriented to the preparation of catalyst which can get high ethylene oligomerization and α-olefin selectivity The ethylene oligomerization initiated by aniline anthraquinone nickel homogeneous system under the activation of different cocatalysts is studied. The results showed that when aluminum compounds with strong Lewis acid such as EtAICI showed high catalytic activity （EtAICI:2.76 x 10 kg/(mol·h);EtAICI:3.1×10kg/(mol·h)；MAO： 3.12×10 kg/ （mol·h catalyst has little catalytic activity.When EtAICI as cocatalyst for activation ALNi ratio is 20 and the pressure is 1.5MPa lytic activity （2.76x10 kg/（mol·h））. Key words:ethylene oligomerization;homogeneous catalysis;aniline-based quinone nickel catalyst;lewis acid cocatalyst aYOYYYYYYYYYYYYYYYYYYYYYYYYYYYY 国内外消息 广州石化首创燃料氢检测新技术 中科炼化产出高附加值EVA新品 近日，广州石化通过技术攻关，实现燃料氢中甲酸、甲 近日，中科炼化10万吨/年EVA （乙烯-醋酸乙烯共聚 醛、硫化物3个项目一次进样同时检测，标志该企业掌握了 物）装置成功产出新产品UE281,为企业拓展了新的效益增 燃料氢14个杂质全项目分析技术，具备自主高效完成燃料 长点，增强了高端聚烯泾产品市场竞争力。 氢检测、出具分析报告的能力。 该产品是热熔胶的主要成分，具有良好的耐药性、热稳 广州石化于2020年12