甲酸盐溶液对饱和盐水磺化钻井液的适应性评价.docxVIP

学兔兔www.xuet ut 石油 与 天 然 气 化 工 614 CHEMICAL ENGINEERING OF OIL GAS 2013 甲酸盐溶液对饱和盐水磺化钻井液的 适应性评价 油气田化学叶 艳1 安 文 华2 尹 达2 赵 姗 姗 梁 红 军2 卢 虎2 李 磊2 油气田化学 (1. 中国石油大学(北京)教育部国家重点实验室 2. 中国石油塔里木油田分公司) 摘 要 超深井多选用高密度饱和盐水磺化钻井液体系，本研究引入高浓度甲酸钾溶液作为 钻井液基液，有效减少高密度钻井液固相含量，提高钻井液及关键处理剂的热稳定性，同时加快超 深井深部巨厚盐岩层钻井速度、减缓钻具腐蚀，充分发挥甲酸盐钻井液良好的抑制性和泥饼质量， 低环空压耗等优势。讨论了重晶石在甲酸钾溶液中的溶解性以及甲酸钾溶液的抗盐抗钙污染能 力，研究结果表明，重晶石在甲酸钾溶液中几乎不溶，所以在饱和盐水磺化钻井液中可用30%~ 70%(w) 甲酸盐溶液提高基液密度，然后采用重晶石进行加重是可行的。此外，氯化钠和石膏在甲 酸盐溶液中的溶解度均有不同程度的降低，可用于进一步提高磺化钻井液的抗盐抗钙污染能力。 关键词 饱和盐水磺化钻井液 甲酸盐基液 重晶石 抗盐钙污染 中图分类号：TE254+.1 文献标志码：A DOI:10.3969/j.issn.1007-3426.2013.06.014 Adaptability evaluation of formate solution to saturated brine sulfonated drilling fluids Ye Yan,An Wenhua2,Yin Da2, Zhao Shanshan,Liang Hongjun2,Lu Hu2,Li Lei2 (1.China University of Petroleum(Beijing),Beijing 102249,China) (2.PetroChina Tarim Oilfield Com pany,Karamay 834000,Xinjiang,China) Abstract: Potassium-based solution with high concentrations is brought into saturated brine sulfonated drilling fluid in the complex ultra-deep wells, which can reduce the solid content of high-density drilling fluid, improve the thermal stability of the drilling fiuid, temperature resist- ance of key treatment agents and the drilling speed in the extremely thick ultra-deep salt forma- tion, and slow down the drilling corrosion. At the same time, formate drilling fluids have the ad- vantages of inhibitive ability, good quality of mud cake, low annular pressure lost and friction co- efficient. This article discussed the solubility of barite in potassium formate solution and its toler- ance to salt and calcium. The experimental results showed that barite was almost insoluble in po- tassium solution so that the formate solution of 30%～70% was