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ExtraProblemsforChapter1–FromCollegeChemistry,page8
1.1Thecolouroflightdependsonitswavelength.Redlighthasawavelengthontheorderof7.8×10-7
m.Expressthislengthinmicrometres,innanometres,andinangstroms.
Ans.0.78mm,780nm,7800Å
1.2Theblueiridescenceofbutterflywingsisduetostriationsthatare0.15μmapart,asmeasuredby
anelectronmicroscope.Whatisthisdistanceincentimetres?Howdoesthisspacingcomparewiththe
wavelengthofbluelight,about4500Å?
Ans.1.5×10-5cm,1/3thewavelength
1.3InacrystalofPt,individualatomsare2.8Åapartalongthedirectionofclosestpacking.Howmany
atomswouldlieona1.00-cmlengthofalineinthisdirection?
Ans.3.5×107
1.4Thebrominecontentofaverageoceanwateris65partsbyweightpermillion.Assuming100%
recovery,howmanycubicmetersofoceanwatermustbeprocessedtoproduce0.61kgofbromine?
Assumethatthedensityofseawateris1.0×103kg/m3.
Ans.9.4m3
1.5Findthevolumeinlitresof40kgofcarbontetrachloride,whosedensityis1.60g/cm3.
Ans.25L
3
1.6Asampleofconcentratedsulfuricacidis95.7%H2SO4byweightanditsdensityis1.84g/cm.(a)
HowmanygramsofpureH2SO4arecontainedinonelitreoftheacid?(b)Howmanycubic
centimetresofacidcontain100gofpureH2SO4?
Ans.(a)1.76×103g;(b)56.8cm3
1.7AquickmethodofdeterminingdensityutilizesArchimedesprinciple,whichstatesthatthe
buoyantforceonanimmersedobjectisequaltotheweightoftheliquiddisplaced.Abarof
magnesiummetalattachedtoabalancebyafinethreadweighed31.13ginairand19.35gwhen
completelyimmersedinhexane(density0.659g/cm3).Calculatethedensityofthissampleof
magnesiuminSIunits.
Ans.1741kg/m3
1.8Apieceofgoldleaf(density19
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