氧化钙高温脱除生活垃圾热处理过程中含氯酸性气体的实验研究.pdfVIP

化。结合文献分析明确了在焚烧气氛下进行高温脱除含氯酸性气体时，CO2对于孔隙活性

位点的促进作用以及硫酸化产物及其共熔物对氯化产物的包裹保护作用，促进了HCl的

进一步吸收，展现了高温脱氯潜力和优势。通过对该组实验数据与动力学模型的拟合，也

发现了产物层扩散控制效果的增强。在850℃下进行了烟气氯硫比、吸收剂种类等其他参

数对于高温脱除含氯烟气影响的实验，指出了钙基吸收剂的在高温下脱除含氯酸性气体的

关键因素，为后续的研究提供参考。

关键词：城市生活垃圾；垃圾焚烧；钙基添加剂；高温脱氯；吸收特性；协同吸收；模型

拟合

Abstract

Theincreaseofmunicipalsolidwaste（MSW）hasbroughttremendouspressureon

environment,resourcesinChina.Inrecentyears,MSWincinerationtechnologywithfeaturesof

reduction,harmlessness,andresourceutilization,hasbeenrapidlydevelopedinourcountry.

However,MSWinourcountryhasacomplexcompositionandhighchlorinecontent.Acidgases

suchasHClgeneratedduringincinerationwillcauseproblemssuchashigh-temperaturecorrosion

andsecondarypollution,whichwillrestrictitsadvantagesineconomyandenvironmental

protection,andrestrictitsfurtherdevelopment.Althoughthefluegastreatmentsysteminthetail

ofplantcanmakethefluegasemissionsmeetincreasinglystrictstandardstoacertainextent,it

cannotavoidthehigh-temperaturecorrosionanddioxinformationcausedbyHCl.Therefore,the

simultaneousremovalofHClandotheracidgasesinthefurnaceathightemperaturecanprovide

thepossibilityforamoreefficientandcleansolutiontotheproblemofMSW.However,the

mechanismandmutualinfluenceofcalcium-basedabsorbentsforthesimultaneousremovalof

differentacidgasesarerelativelycomplicated,andtheresearchinthisareaisrelatively

insufficient.Therefore,furtherresearchandexplorationinthisareahavecertainengineering

significanceandeconomicpotential.

Firstly,thispaperusesthethermodynamicsimulationsoftwareFactSagetopreliminarily

exploretheregularpatternoftemperature,composition,reactionratioan