OLED器件工作原理与结构组成.pptxVIP

ElectrontransportlayerHoletransportlayerAnodeSubstrateEmissivelayerElectronInjectionlayerCathodeHoleInjectionlayerHOMO—EvLUMO—EcTransparentsubstrateITOHILHTLEMLETLEILCathodeh+e-h+h+e-e-LightElectronsinjectedfromcathodeHolesinjectedfromanodeTransportandradiativebinationofelectronholepairsatemissivelayer1SmallmolecularOLEDs—DeviceoperationprincipleHOMO,LUMOoftheHTLisslightlyabovethatoftheETL

n-typematerials(ElectronInjectionLayer)Alq3:tris(8-hydroxyquinoline)aluminumElectronTransportLayerPBD:2-(4-biphenyl)-5-(4-t-butylphenyl)-1,3,4-oxadiazolep-typematerialsHIL(HoleInjectionLayer):NPBHTL(HoleTransportLayer):TPDEML:(EmmisiveLayer)Fluorescentdye:DCM2PhosphorescentdyePtOEP,Ir(ppy)3

p-typematerialsHIL(HoleInjectionLayer):NPBHTL(HoleTransportLayer):TPDEML:(EmmisiveLayer)Fluorescentdye:DCM2PhosphorescentdyePtOEP,Ir(ppy)3DCM2

2MolecularLuminescenceThreetypesofLuminescencemethodsare:Fluorescence:absorptionofphoton,short-livedexcitedstate(singlet),emissionofphoton.Phosphorescence:absorptionofphoton,long-livedexcitedstate(triplet),emissionofphoton.Chemiluminescence:noexcitationsource–chemicalreactionprovidesenergytoexcitemolecule,emissionofphoton.Luminescence:Highsensitivity?strongsignalagainstadarkbackground.UsedasdetectorsforHPLCCE.

SingletandtripletstatesGroundstate:–twoelectronsperorbital;electronshaveoppositespinandarepairedSingletexcitedstate:ElectroninhigherenergyorbitalhastheoppositespinorientationrelativetoelectroninthelowerorbitalTripletexcitedstateTheexcitedvalenceelectronmayspontaneouslyreverseitsspin(spinflip).Thisprocessiscalledintersystemcrossing.Electronsinbothorbitalsnowhavesamespinorientation

PrinciplesofFluorescenceFluorescenceprocess:Non-radiativerelaxationIntheexcitedstate,theelectronispromotedtoanantibondingorbital→