有机化学-烯烃制备-消去反应.pptxVIP

XYdehydrogenationofalkanes:

X=Y=Hdehydrationofalcohols:

X=H;Y=OHdehydrohalogenationofalkylhalides:

X=H;Y=Br,etc.abCCCC+XYb-EliminationReactionsOverview

limitedtoindustrialsynthesesofethylene,

propene,1,3-butadiene,andstyrene importanteconomically,butrarelyusedin

laboratory-scalesyntheses

750°CCH3CH3750°CCH3CH2CH3H2CCH2+H2H2CCHCH3+H2Dehydrogenation

5.9

DehydrationofAlcohols

(79-87%)(82%)H2SO4160°CCH3CH2OHH2CCH2+H2OH2SO4140°C+H2OCOHCH3CH3H3CH2SO4heatCH2H3CCH3C+H2ODehydrationofAlcoholsOH

tertiary:

mostreactiveprimary:

leastreactiveRRROHCRRH