碳微球的荧光量子效应.docVIP

  碳微球的荧光量子效应# 宋静静1,2，李勇1,2，韩艳星1,3，杨永珍1,4，刘旭光1,3，许并社1,4** （1. 太原理工大学新材料界面科学与工程重点实验室，太原 030024； 5 10 15 2. 太原理工大学材料科学与工程学院，太原 030024； 3. 太原理工大学化学化工学院，太原 030024； 4. 太原理工大学新材料工程技术研究中心，太原 030024） 摘要：碳量子点是一类有发展和应用前景的新型荧光纳米材料，与半导体量子点等其它荧光 纳米颗粒相比有其独特的优点，可广泛应用于太阳能电池、发光器件和光学生物标记等领域。 本文首先利用化学气相沉积法以乙炔为碳源制备碳微球（CMSs），然后用壳聚糖（CS）和 SiO2 两种不同性质的材料对 CMSs 进行了化学修饰的研究，得到 CS/CMSs 和 SiO2/CMSs 复 合物，最后考察 CMSs 及其复合物在 254nm 紫外灯激发下的荧光性，讨论不同溶剂和不同 浓度对 CMSs 及其复合物荧光性能的影响。采用场发射扫描电子显微镜、傅里叶变换红外光 谱分析仪和荧光光谱仪对产物进行了表征和分析。结果表明：不同浓度的原始 CMSs、氧化 CMSs、CS/CMSs 和 SiO2/CMSs 在有机溶剂（乙醇和 CCl4）和水中发出不同颜色的荧光， 随着溶剂极性的增加，荧光颜色向长波方向移动（紫色→黄色），且随着浓度的增加，颜色 逐渐加深，浓度太大时会发生荧光猝灭。 关键词：材料物理与化学；碳微球；碳量子点 中图分类号：TB 332 20 Fluorescence quantum effect of carbon microsphere SONG Jingjing1,2, LI Yong1,2, HAN Yanxing1,3, YANG Yongzhen1,4, LIU Xuguang1,3, XU Bingshe1,4 (1. Taiyuan University of Technology, Key Laboratory of Interface Science and Engineering in 25 30 35 40 45 Advanced Materials , Ministry of Education, TaiYuan 030024; 2. Taiyuan University of Technology, College of Materials Science and Engineering, TaiYuan 030024; 3. Taiyuan University of Technology, College of Chemistry and Chemical Engineering, TaiYuan 030024; 4. Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, TaiYuan 030024) Abstract: Carbon dots (C-Dots), an advanced fluorescent nanomaterial, which have good prospects for development and application. Based on these advantages compared to quantum dots (QDs) and other fluorescent nanoparticles, C-dots could replace QDs in the scientific fields such as solar cells, luminescent device and optical biomarkers. carbon microspheres (CMSs) were prepared by chemical vapor deposition using acetylene as carbon resource; than, CMSs were modified by chitosan (CS) and SiO2; finally, the fluorescence of CMSs and their composite were study with ultraviolet lamp (excited at 254 nm), in which the effects of solvent and concentration of suspension were considered. Field emission scanning