溴化丁基橡胶产品微观结构分析及测试.pdfVIP

I 不饱和度 溴含量 溴化丁基橡胶 ：关键词 支持。理论 三种方法，能够表征出溴化丁基橡胶的产品性能，对研究丁基橡胶的溴化反应提供了 定溴化丁基橡胶的不饱和度，这种方法操作简单方便，精确度也比较高。通过使用这 另外，还考察了环氧滴定法测 法基本吻合，操作简单方便，也可考虑用于工业生产。 振电位滴定法的测试结果与核磁共-氧弹确度较高，可用于工业生产，但成本较高，而 准法测定溴含量 H-NMR 测定溴化丁基橡胶的溴含量。结果表明，电位滴定法-察了氧弹 1 考着重 谱图表征溴化丁基橡胶的微观结构并计算其溴含量，H-NMR 本文主要利用 1 要 摘 溴化丁基橡胶产品微观结构分析及测试 溴化丁基橡胶产品微观结构分析及测试 ABSTRACT Using the 1H-NMR spectrogram the microscopic structure of bromobutyl rubber is characterized. The bromine content of bromobutyl rubber determined by oxygen bomb - potentiometric titration and 1H-NMR spectroscopy. The result indicated that the analytic result of 1H-NMR spectroscopy is correct and relative accurate, and the method is able to use for industrial analysis. But its cost is high. Otherwise the analytic result of oxygen bomb - potentiometric titration is nearly the same to that of nuclear magnetic resonance .The operation of oxygen bomb - potentiometric titration is simple, and it also can be used for industrial analysis. Moreover, a simple method of epoxidation titration is used to test the unsaturation of the bromobutyl rubber. This method is easy to operate and its result is correct. These three methods which front mentioned can be used to truely characterize bromobutyl rubber’s properties, providing the theory support to the study of the butyl rubber’s bromination reaction. KEY WORDS: bromobutyl unsaturation bromine content II 溴化丁基橡胶产品微观结构分析及测试