东江惠州段干流及支流沉积物中磷的形态分布特征.doc

  东江惠州段干流及支流沉积物中磷的形态 分布特征# 于飞1,2，杨扬1,2，乔永民1,2** 5 10 15 20 25 30 35 40 45 （1. 暨南大学水生生物研究所，广州 510632； 2. 热带亚热带水生态工程教育部工程研究中心，广州 510632） 摘要：2011 年 3 月采集东江惠州段干流及入江支流 19 个表层沉积物样品，采用欧洲标准测 试法(SMT)分析了的磷形态，探讨了沉积物磷的形态分布特征及来源和释放潜力，结果表明： 沉积物中总磷(TP)含量范围在 576.3~2627.3mg·kg-1，最大值和最小值分别出现在 XK2 和 XK3 号点，其入江支流显著高于国内许多河流。无机磷(IP)含量范围在 275.0~2738.2 mg·kg-1，占 TP 的 42.6%~104.2%。有机磷(OP)含量范围在 146.5~417.7 mg·kg-1，占 TP 的 11.3%~45.5%。 TP 的分布主要受 IP 的控制，在 IP 中，钙结合态磷(HCL-P)，含量范围在 56.6~290.3 mg·kg-1， 占 IP 的 3.6%~29.9%；铁/铝结合态磷(NaOH-P)含量范围在 216.0~2329.5 mg·kg-1，是主要部 分，占 IP 的 76.6%~111.9%。入江支流表层沉积物向上覆水体释放磷的潜力较大。沉积物中 NaOH-P 含量与活性态 Al 含量相关性显著(p 0.05)，与活性态 Fe 的含量相关性极显著(p 0.01)。 关键词：环境科学；城市河流；沉积物；磷形态；东江 中图分类号：X5 Distribution characteristics of phosphorus forms in surface sediments of the dongjiang river and its tributaries in Huizhou YU Fei1,2, YANG Yang1,2, QIAO Yongmin1,2 (1. Research Center of Hydrobiology, Jinan University, GuangZhou 510632; 2: Ministry of Education Engineering Research Center of Tropical and Subtropical Aquatic Ecological Engineering, GuangZhou 510632) Abstract: Contents and distributions of different forms of phosphorus were determined for 19 surface sediments collected from Dongjiang river and its tributaries in Huizhou, China, in March 2011. Forms of phosphorus in sediments were analyzed using the Standards Measurements and Test (SMT) procedure of phosphorus forms in freshwater sediments. Results showed that the concentration of Total Phosphorus(TP) in the sediments ranged from 576.3 mg·kg-1 in XK3 to 2627.3 mg·kg-1in XK2. The Inorganic Phosphorus(IP) was the dominant portion of phosphorus, whose concentration ranged from 275.0 mg·kg-1 to 2738.2 mg·kg-1, accounting for 42.6% to 104.2% of TP. The Organic Phosphorus(OP) concentration was 146.5~417.7 mg·kg-1，accounting for 11.3%~45.5% of TP. Phosphorus bound to Fe/Al oxides and hydroxides(NaOH-P), which was the active species ,ranged from 216.0 mg·kg-1 to 2329.5 mg·kg-1 accounting for 76.6%~111.9% of IP. Space distribution of