以木质素磷酸酯季铵盐为模板剂直接沉淀法制备氧化锌介孔材料.docVIP

  Synthesis of mesoporous ZnO by direct precipitation with Lignin-phosphate quaternary ammonium salt# 5 10 15 20 25 30 35 40 Yuanru Guo1, Fangdan Yu2, Qingjiang Pan3, Guizhen Fang2* (1. College of Material Science and Engineering, Northeast Forestry University, 150040, Harbin, , 150040; 2. College of Material Science and Engineering, Northeast Forestry University; 3. Key Laboratory of Functional Inorganic Material Chemistry of Education Ministry, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China) Abstract: In this paper ， Mesoporous-ZnO crystals were prepared in aqueous solutions with Lignin-based surfactant(Lignin-phosphate quaternary ammonium salt，LPAS) by one step. X-ray diffraction(XRD) studies show that fine hexagonal wurtzite ZnO particles can be obtained with diameter of 20-40nm. SEM studies reveal that different concentrations of LPAS can affect the Morphology of ZnO. The ball particles can be obtained by low concentration of LPAS. TEM give the evidence that mosopores are found in ZnO crystals and with the average pore size of 36nm according to the Brunauer-Emmett-Teller (BET) measurement. Key words: Lignin-phosphate quaternary ammonium salt; ZnO crystal; mesopores 0 Introduction Due to a direct wide band gap (3.37 eV) and large excitation bindingenergy (60 meV) at room temperature, zinc oxide (ZnO) can be used as semiconductors with excellent properties and extensive applications in electronics, photoelectronics, sensors and catalyses. Morphology of the ZnO crystal can affects its physical properties, therefore, ZnO micro-/nano-crystals in a variety of shapes, such as nanoparticles , nanowires, nanorods , tubes, films, have been synthesized and investigated[1-5]. More recently, two-dimensional (2D) porous ZnO nanosheets combining unique sheet-like morphology and porous structure have attracted great research interests because of their significantly enhanced properties in photoluminescence and gas sensor applicatio