微波加热化学活化法制备活性炭的优化工艺研究.pdfVIP

第44卷第1期 生摇 物摇 质摇 化摇 学摇 工摇 程 Vol.44 No.1 2010年1月 Biomass Chemical Engineering Jan. 2010 蕰藭蕰蕰蕰蕰蕰蕰蕰藭蕰蕰 研究报告 藭蕰蕰蕰蕰蕰蕰蕰蕰 藭 微波加热化学活化法制备活性炭的优化工艺研究 谭 非,王彬元,林金春,黄 彪* (福建农林大学材料工程学院, 福建 福州 350002) 摘摇 要:研究了微波加热条件下碳酸钾活化制备活性炭的工艺流程。 以碳酸钾为活化剂,微波为热源,采用正交试验,研 究了浸渍时间、活化剂浓度、微波功率、微波加热时间对活性炭产品性能碘吸附值、亚甲基蓝吸附值、得率的影响规律,得 到了最佳工艺条件,即微波功率600W、微波加热时间6min、碳酸钾浓度0.20g/ mL、浸渍时间24h。 制得活性炭的碘吸 附值可达1189.68mg/ g、亚甲基蓝吸附值 190mL/ g、得率29.48%,在该工艺条件下,制备的活性炭试样比表面积为 2 3 3 1186.10m / g,总孔容积0.624cm / g,微孔容积0.407cm / g,吸附性能较国家标准有所提高。 关键词:微波加热;松木屑;活性炭;吸附 中图分类号:TQ424.19摇 摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 摇 文章编号:1673-5854(2010)01-0001-04 Optimization Technology for Preparation of Activated Carbon with Chemical Activation by Microwave Heating Method TAN Fei,WANG Bin鄄yuan,LINJin鄄chun,HUANG Biao (College of Material Engineering,Fujian Agriculture and Forestry University,Fuzhou350002,China) Abstract:This paper studied the potassium carbonate as the chemical activator for activated carbon preparation by microwave heating. With potassium carbonate as the activator andmicrowave astheheat source,the effectsof impregnatingtime,chemical activator concentration,activation time and microwave power on the adsorption properties of activated carbons were studied by orthogonal test and the optimal results were obtained. The optimal results are microwave power 600W,microwave time 6min, chemical activator concentration 0.20g/ mL and impregnating time 24h. Iodine adsorption value of activated carbon reached 1189.68mg/ g and ethylene blue discoloring ability of activated carbon reached 190mL/ g,and the yield was 29.48%. The 2 3 specific sur