用于选择性去除水中汞和铯的新型高分子螯合纤维论文.pptVIP

Novel Polymeric Chelating Fibers forSelective Removal of Mercury andCesium from Water用于选择性去除水中汞和铯的新型高分子螯合纤维 author ：C H U N Q I N G L I U , Y O N G Q I N G H U A N G ,N A T H A N I E L N A I S M I T H , A N D J A M E S E C O N O M Y years：Environ. Sci. Technol. 2003, 37, 4261-4268 something about the thesis Abstract： We report here the synthesis and characterization of two new classes of chelating fibers, namely： (1) polymercaptopropylsilsesquioxane（巯聚倍半硅氧烷） (PMPS) and (2) copper(II)Ferrocyanide（亚铁氰化铜） complexed with poly[1-(2-aminoethyl)-3-aminopropyl]silsesquioxane （聚[1 - （2 - 氨基乙基）-3- 氨基丙基]硅倍半氧烷）(Cu-FC-PAEAPS) fibers. These fibers were evaluated for selective removal of trace amount of mercury and cesium ions respectively in the presence of competing metal ions from water 翻译： 通过分别跟踪存在竞争金属离子的汞离子和铯离子的水溶液来评价它们的去离子能力。 These novel materials are extremely efficient in removing low concentrations of mercury and cesium ions from water in the presence of high concentrations of sodium or potassium ions. 翻译： 这些新型材料在从高浓度的钠离子或钾离子溶液中除去低浓度的汞和铯离子方面是非常有效的。 They were shown to remove trace mercury and cesium contaminants effectively to well below parts per billion concentrations under a variety of conditions. 翻译： 他们可以在远低于十亿分之一各种条件的浓度下有效除去痕量汞和铯污染物。 Introduction： Mercury pollution has been identified as a serious problem at waste-contaminated sites 引言： 在废物污染的网站，汞污染已被确定为一个严重的问题。 Reasons： (1). One estimate of the total annual global input of mercury to the atmosphere from all sources including natural, anthropogenic, and oceanic emissions is 5500 tons (2), prompting the establishment of increasingly stringent government regulations demanding that levels of this contaminant be lowered. Radioactive cesium contamination of water is also of serious social and environmental concern since it is a significant fraction of theradioactivity of the liquid waste (3). The separation of mercury and cesium from various solutions has been done for many years principally using ion e