CVD法制备(Fe,Cr,Mn)硅化物纳米线及性能研究.pdf

摘 要 纳米材料具有小尺寸效应、量子效应（含宏观量子隧道效应）、表面效应 和界面效应，因此表现出块体材料所不具备特殊的物理、化学性能。一维纳米 材料在磁、热、光、电、催化、生物等方面具有独特的性质，有望在诸多领域 得到广 的应用。 由于FeSi 具有温度依赖的独特电磁性能和在自旋电子学方面的潜在应用， 近年来吸引了越来越多的研究。我们采用简易、可控的化学气相沉积法一步生 长了FeSi 一维纳米结构，并表征了相应的晶体结构和位向关系，Si[0 0 1] // Fe O [ 2 0 1], Si (0 0 1 ) // Fe O (1 0 2). 。通过探讨和分析其生长机理，分析了各 3 4 3 4 制备参数，如温度、气压、时间、流量等对FeSi 纳米线生长的影响，并通过调 控这些参数初步实现了对FeSi 纳米线阵列的尺寸、形貌、生长方向、有序排列 和组装等方面的调控。我们成功制备了具有纳米Fe3O4 磁性头的FeSi 纳米线， 磁性能的测量表明纳米Fe3O4 磁具有较强的磁性，矫顽力在 10K 时为 220 Oe 。 FeSi2 是优异的热电材料，我们通过掺杂和气氛退火等方法成功生长了直立型到 的FeSi2 纳米线。同时初步探索了Cr、Mn 的硅化物纳米线和一维超晶格结构的 生长。 ; ; ; 关键词：化学气相沉积 硅化物 纳米线 超晶格 Abstract The novel properties of nano-materials due to the special structure of nano-materials, make them show four maj or effects: small size effect, quantum effect (including macroscopic quantum tunneling effect), surface effect and interface effect, which are not observed in bulk materials, nano-materials have superior physical and chemical properties. As one-dimensional nano-materials have peculiar characteristics in magnetic, thermal, optic, electronic, catalytic and biological aspects, they have prospect of extensive applications in many fields. As FeSi has special temperature-dependent electronic and magnetic performances , it has promising potential application in Spintronics , and attracted a growing number of studies in recent years. Using simple and controllable chemical vapor deposition method, we have successfully growed one-dimensional nanostructure of FeSi by one step, and characterized its crystal structure and orientation relationship : Si[0 0 1] // Fe O [ 2 0 1], Si (0 0 1 ) // Fe O (102). Via