电刷镀纳米结构镀层的发展及其机理研究走向冰.pdfVIP

1 第21卷 第5期 中 国 表 面 工 程 、，01．21 No．5 2008年 l0月 CHINA SURFACE ENGINEERrNG October 2008 电刷镀纳米结构镀层的发展及其机理研究走向冰 谭 俊 ，田 辉 ，高玉琳 ，石恭臣 (1．装备再制造技术国防科技重点实验室，北京 100072；2．石家庄高新区供水排水公司，石家庄 050801) 摘 要：对电刷镀纳米结构镀层，包括纳米晶镀层、纳米颗粒复合镀层、纳米纤维复合镀层和纳米多层镀层的制备、 性能及其应用进行了综述。提出了电刷镀纳米结构镀层相关机理的研究重点是：从电刷镀溶液高的金属离子含量、高 的过电位和摩擦作用等对镀层形核与生长的影响研究电刷镀纳米晶的形成机理；从纳米第二相在镀液中的分散状态与 负电特性及其对复合镀液特性的影响等研究复合电沉积机理；并用材料物理的方法开展强化机理的定量研究和用热力 学的方法分析复合镀层的高温强化机理。 关键词：电刷镀；纳米晶；纳米结构镀层；复合镀层；复合沉积机理；强化机理 中图分类号：TG174．441 文献标识码：A 文章编号： Brush Plating Nano-Structured Coating and its Mechanism Research Trend TAN Jun，GAO Yu—lin，SHI Gong—chen (1．National Key Laboratory For Remanufacturing，Beijing 1 00072；2．Shijiazhuang High—tech Developing Zone Water Supply Discharing Company,Shijiazhuang 050801 1 Abstract：The preparation，properties and application of brush plated nano—structured coatings，which including nano—cryatalline coating，nano—particle composite coating，nano—fiber composite coating and nano—multilayer were reviewed．The paper put out the emphasis of mechanisms studies related with brush plated nano—structured coatings，including the investigation on the nano—cryatalline formation mechanism from the influence of high metallic ions content in the solution，hi【gh over and friction between brush and work piece on the ulceration and growth；the CO—deposition mechanism from the dispersion and electric charging of the second nano phases and their influence on the solution properties；the strengthening mechanism by material physical method quantitatively and the high temperature strengthening mechanism by thermodynamic m~hod． Key words：brush plating；nano—crystalline；nano．-structured coating；composite coating；CO—deposition mechanism； strengthening mechanism 0 引 言