长链烯烃与苯烷基化反应技术评析.pdfVIP

化学通报 2003 年 第66 卷 w033 长链烯烃与苯烷基化反应技术述评 1,2 1* 1 乔聪震 李成岳 张金昌 1 2 ( 北京化工大学可控化学反应科学与技术基础教育部重点实验室 北京 100029 河南大学化学化工学院 河南开封 475001) 摘 要 介绍了长链烯烃与苯烷基化的催化剂及反应技术现状 生产线性烷基苯的传统工艺使 用HF 或AlCl3 作催化剂 污染严重 在不断开发新型满足绿色化学要求的催化剂同时 新的反应技 术如固定床 催化蒸馏 液-固循环流化床和悬浮床催化蒸馏技术也相继出现 但只有UOP 公司的Detal 工艺实现了工业化 进一步的研究应着眼于开发低温活性好 选择性高并且在工业条件下寿命长的 环境友好催化剂 同时相应地革新反应与分离技术 进而改善反应分离系统的综合性能 关键词 苯 长链烯烃 烷基化 反应技术 Review of Reaction Technology for Alkylation of Benzene with Long Chain Alkenes 1,2 1 1 Qiao Congzhen , Li Chengyue , Zhang Jinchang 1 ( The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Tehnology, Beijing 100029 2Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001) Abstract This paper reviews the status of catalyst and reaction technology for alkylation of benzene with long chain alkenes. Conventional methods for the production of linear alkylbenzene generally use HF or AlCl3 as acid catalysts. These processes feature serious environmental drawbacks. Along with the development of new green catalysts, various new reaction technologies such as fixed-bed, reaction- distillation, liquid-solid cycling fluidized bed and suspension catalytic distillation were proposed and introduced to this reaction system, although at present only the UOP Detal technology has been commercialized. Further studies