金多壁碳纳米管的制备及其对曲酸的.docVIP

多壁碳纳米管的制备及其还备纳MWCNT’s）负载的Au纳米粒子催化剂。首先通过法对MWCNT’s进还剂柠钠为稳剂还属前驱备纳TEM、XRD、红谱仪对进结纳将修饰电Au/MWCNT’s），在最优化的实验条对进电学检测，该对线围为：1.0×10-3 - 5.5×10-3 mol/L检测为：2×10-5 mol/L，表明该对电学检测线围宽，灵点纳纳Preparation of carbon nanotubes supported Au nanoparticles and electrochemical performance for kojic acid Ma Jian-chun Wang Zhong-hui Kang Yan-zhen (Department of Chemistry and Chemical Engineering, Lvliang College, Lvliang 033000, China) Abstract: The gold nano-particles modified multi-walled carbon nanotubes (MWCNT’s) were prepared using ethylene glycol reduction method. Firstly, MWCNT’s were functionalized by immersing in mixed acids. Then, metal precursor, HAuCl4·3H2O was reduced by ethylene glycol in a solution containing sodium borohydride as reducing agent, sodium citrate as a stabilizer. The Au nanoparticles-loaded carbon nanotubes composite was characterized using TEM, XRD, infrared spectrometer. The results show the gold nanoparticles were successfully supported onto the carbon nanotubes. Kojic acid was studied by electrochemical detection in the optimized condition with gold nanoparticles-loaded carbon nanotubes composite as the modified electrode (Au/MWCNT’s). Experimental results show that the composite materials have good catalytic performance for kojic acid, the linear range is 1?i0-3-5.5×10-3 mol/L (S/N=3), the limit of detection is 2.0×10-5 mol/L. The composite materials by ethylene glycol reduction preparation have wide linear range, high sensitivity for kojic acid. Key words: Carbon nanotubes; Au nano-particles; kojic acid 曲酸C6H6O4，化学名称为5-羟基-2-羟甲基-14-吡喃酮存在于酒类、豆瓣酱酱油的酿造中，在许多以曲霉发酵的发酵产品中都可以检测到曲酸进入后能够抑制黑色素的形成[1-2]，曾被用于美白类化妆品中；曲酸还具有清除自由基、增强细胞活力、食品保鲜护色等作用，被用于医药和食品领域近年来的研究表明曲酸具有致癌性，[3-4]等，这些检测方法不仅成本高，实验过程复杂,而且实验结果准确度较差。近年来很多研究者开始采用电化学方法对曲酸进行检测[5-7]。 自1991年发现碳纳米管[8]以来，由于其具有独特的物理和化学特性[9-10]，在储氢剂级电锂电纳米电金属粒子的尺寸就会特殊的化学性质，’s）进行功能化，之后用乙二醇还原金的前驱体三水合氯金酸溶液，制备出Au/MWCNT’s纳米复合材料，并用其修饰玻碳电极对曲酸进行电化学检测。 1 试验部分 .1 仪器试剂 岛津XD-3A 型X射线衍射仪Philips CM 300 FEG型透射电子显微镜 Tensor 27型傅叶红外光谱仪 CHI 660C型电化学1.2 仪器工作条件