外墙外保温挤塑聚苯板专用界面剂的研制.pdfVIP

全国中文核心期刊 杆 建巍 夕墙夕保温挤塑聚苯板 苣用界面剂硇硼制 王建方，毛明富，龚雁，陈明清 (江南大学 化学与材料工程学院，江苏 无锡 214122) 摘要：采用预乳化——半连续种子乳液聚合方法合成了外墙外保温挤塑聚苯板专用界面剂醋丙乳液，通过分别引入丙烯酸 (AA)、聚乙二醇大分子单体 (PEGMA)、丙烯酸羟乙酯 (HEA)、甲基丙烯酸缩水甘油酯 (GMA)和丙烯酰胺 (AM)等功能性单体以改善 对挤塑聚苯板 (XPS)的粘结强度。探讨了单体的配比组成、引发剂与乳化剂用量、乳化温度等对界面粘结强度的影响。结果表明，合 成的专用界面剂乳液能明显提高XPS与砂浆的拉伸粘结强度，克服XPS板因表面光滑且呈高疏水性而造成的空鼓脱落、粘结不 良 的现象，得出了最佳专用界面剂乳液的聚合反应配方。 ． 关键词：挤塑聚苯板(XPS)；界面剂；醋丙乳液；粘结强度 中图分类号：TQ331．4 文献标识码：B 文章编号：1001—702X(2010)12-0054—04 Developmentofexclusiveinterfaceagentfor XPS board in exterior wallexternalinsulation system WANGJianfang，MA0MinglJ*，GONG Yan，CHENMingqing (SchoolofChemicalandMaterialEngineering，JiangnanUniversity，Wuxi214122，Jiangsu，China) Abstract：Exclusive interfaceagentofvinylacetate—-acrylate emulsion wassynthesized through pre——emulsified and semi—_ continuousseed emulsion polymerization，which wasused in exteriorwallexternal insulation system ofextruded po lystyrene board (XPS)．Thefunctionalmonomersuchasacrylicacid (AA)，polyethyleneglycolmacromonomer (PEGMA)，2-Hydmxyethylacrylate (HEA)，glycidylmethacrylate(GMA)andaerylamide(AM)wasrespectively introducedtothelatexto improvethebondstrengthon XPS．Th e influences of composition ratio，amountof initiator and emulsifier，and pre-emulsifying temperature on the interfacial bond strength were also discussed．The results showed that exclusive interface agentcould significantly increase the tensile bond strengthbetweenXPSboardand mortar．Th ereforethedefectssuch asbubblingoff andpoorbonding causedby smooth surface and highlyhydrophobieofXPS could beovercome．Finally an optimum emulsion polymerization formulation ofexclusive interface agentWas obtained．