软水密闭式循环冷却系统绿色钢铁缓蚀剂的研制.pdfVIP

第 17 卷 第 2 期 腐蚀科学与防护技术 Vol 17 No2 2005 年 3 月 　　　　 　　　　 Mar 2005 CORROSION SCIENCE AND PROTECTION TECHNOLOGY 软水密闭式循环冷却系统绿色钢铁缓蚀剂的研制 郑逸云, 周柏青 , 李芹 武汉大学水质工程系 , 武汉 430072 摘要 :选定 4 种不同类型的缓蚀剂进行正交配方试验 ,得到了软水钢铁缓蚀剂优化配方 GSZ - 2 。GSZ - 2 在使用 剂量 41 mg/ L 时 , 软水中碳钢的腐蚀速率为 0. 0298mm/ a , 药剂成本仅为 0. 682 元/ 吨水 , 其排放能完全达到 GB8978 - 1996《污水综合排放标准》要求。综合性能、经济性、环境影响性, GSZ - 2 是软水密闭式循环冷却系统优 良的钢铁缓蚀剂配方,极具推广价值 ,市场潜力很大。 关键词 :软水 ;密闭循环 ;缓蚀剂 中图分类号: TG17442 　　文献标识码 :A 　　文章编号 :(2005) A GREEN CORROSION INHIBITOR FOR STEEL IN SOFT WATER IN CLOSED CIRCULATING COOL ING SYSTEM ZHEN G Yiyun ,ZHOU Baiqing , L I Qin Depart ment of W ater Qulity Engineering , W uhan U niversity , W uhan 430072 ABSTRACT:This paper is aiming to solve soft water corrosion of steel for closed circulating cooling systems. On trial tests of inhibition performance of some existent corrosion inhibitors individually or combinationally ,an optimal formula GSZ - 2 consisted of sodium molybdete ,zinc sulfate , hydroxy - acid amide and PB TCA was obtained ,which has favourable corrosion inhibition performance for steel in soft water. With 41mg/ L GSZ - 2 , the corrosion rate of steel in soft water is 0. 0298mm/ a ,and there by the water quality meets the requirement of GB8978 - 1996 Integrated Waste Water Discharge Stan dard. In view of its all round performance ,including economical efficiency and environmental influence etc. GSZ - 2 is an excellent corrosion inhibitor for steel in soft water for closed circulating cooling sys tem. KEY WORDS :soft wat