温度对CFVE复合材料等温固化过程的影响.pdfVIP

温度对CF/VE 复合材料等温固化过程的影响 1 1 2※ 1 石海洋 李鹏 薛忠民 杨小平 （1.北京化工大学国家碳纤维工程技术研究中心；2.北京玻璃钢研究设计院 102101) 关键词：乙烯基酯树脂；碳纤维；复合材料；固化；DMTA；DSC EFFECT OF TEMPERATURE ON THE CURING PROCESS AND PROPERTIES OF CF / VE COMPOSITE 1 2* 1 1 SHI Hai-yang ，XUE Zhong-min , LI Peng , YANG Xiao-ping （1. Institute of Carbon Fiber and Composites, Beijing University of Chemical Technology,2.Beijing FRP research of Chemical Technology, 100029, China ） Abstract: The isothermal curing of carbon fiber /vinyl-ester resins (CF/VE) composites was scanned by Dynamic Mechanical Thermal Analyzer (DMTA) and Differential scanning calorimeter(DSC) at different temperature, and then post curing was rescanned by DSC, composites was scanned by DMTA after isothermally curing with and without postcure. Composite’s samples were made and LISS of it was conducted. The results show that: microheterogeneity will occur during curing when temperature of isothermal cure is low; the postcure can improve the LISS of isothermal cured composites about 55.64 ％ when the isothermal curing temperature is 90℃, however, the postcure doesn’t work if the isothermal curing temperature was 120℃. Key words: vinyl ester resins carbon fiber composites cure DMTA DSC 乙烯基脂树脂具有优异的耐腐蚀性能，碳纤维具有很好的力学性能，二者的 [1-2] 复合材料在不同领域得到了广泛的应用 。对于乙烯基脂树脂的固化反应及机理 迄今为止已经进行了广泛的研究，如应用DSC 量热扫描测试化学反应过程中的反 应热，应用红外光谱分析研究树脂在反应过程中的官能团变化[3－6] ，但是热固性树 脂作为复合材料的基体树脂使用，树脂的固化行为受到纤维－基体树脂界面的影 1 [7－9] 响，纯树脂的固化行与复合材料的固化行为相差较大 ，因此在复合材料环境下 研究树脂的固化过程及工艺更具有实际意义。DMTA 技术（动态机械分析）已经 被广泛地应用于聚合物的表征，不同于其它的研究方法，它能研究一定条件下材