DSSC电池及其光敏化染料的选择、定位研究.pdfVIP

中国科技论文在线 DSSC 电池及其光敏化染料的选择、定位研 究# 古丽米娜，姚建曦* 5 （华北电力大学可再生能源学院新能源电力系统国家重点实验室，北京 102206 ） 摘要：染料敏化太阳电池 （DSSC ）是一种非传统的、有机金属的、仿生的、激子的新型太 阳电池，已引起各国科学家的广泛关注，属于新兴的光电材料热点研究领域。而对于高效 DSSC ，其光敏化染料的光谱吸收特性、化学稳定性及与薄膜电极的匹配性是决定DSSC 光 10 电转换效率的关键因素之一。因此，可通过对具有不同光吸收特性的染料进行选择，进而 将其在 DSSC 多孔薄膜电极中的不同区域进行定位吸附，利用其在吸光带上的互补，实现 薄膜电极对可见光吸收范围的大大增加，达到提高 DSSC 光电性能的目的。从而，为设计 和制备具有高光电转换效率的太阳电池奠定基础，对获取高效、廉价、环保的光电材料提 供了理论依据和实验基础，必将大大促进我国在光电功能材料方面的研究。 15 关键词：染料敏化太阳电池；光敏化染料；光吸收特性；薄膜电极 中图分类号：TB34 DSSC solar cell and the research of choosing and positioning of the photosensitization dyes 20 Guli Mina, Yao Jianxi (State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, Renewable Energy School, North China Electric Power University, Beijing 102206) Abstract: Dye sensitized solar cell (DSSC) is a kind of unconventional, organic metal, bionics, excitonic new kind of solar cell, and it has caused the extensive concern of scientists all over the 25 world. It belongs to the research field of emerging photoelectric materials. But for efficient DSSC, the spectral absorption characteristic, chemical stability of photosensitization dyes and matching with the thin film electrode is one of the key factors for DSSC photoelectric conversion efficiency. Therefore, the selection of photosensitive dyes with different light absorption characteristic, and the positioning adsorption in different area in the porous film electrode, will greatly increase the 30 range of visible light absorption in the thin film electrode, and improve the photoelectric property of DSSC. Accordingly, it will l