光诱导还原纳米银修饰硅纳米线阵列活性基底的SERS研究.pdfVIP

中国科技论文在线 光诱导还原纳米银修饰硅纳米线阵列活性 基底的SERS 研究 1 1 2** 石美霞 ，丁建华 ，吴世法 5 （1. 大连理工大学物理与光电工程学院，辽宁大连 116024； 2. 大连理工大学物理与光电学院，辽宁大连 116024 ） 摘要：采用温度控制法制备出硅纳米线（SINWs ）阵列，表面渡一层TiO2 薄膜作为衬底， 紫外光诱导在其表面自组装纳米银修饰（Ag/SINWs ），并以R6G 作为探针分子来检测这种 10 Ag/SINWs 基底的表面增强拉曼散射（SERS ）效应的增强活性和保持时间。实验结果显示 Ag/SINW 活性基底能清晰的检测出10-9mol/L 浓度的R6G 的特征谱，并且具有良好的SERS 效应均匀性和可重复性。研究还发现Ag/SINWs 活性基底具有一定的稳定性，在室温条件下 存放30 天后对于10-7 mol/L 浓度的R6G 依然能检测出特征峰，是一种新型的SERS 活性基 底。 15 关键词：硅纳米线（SINWs ）；光诱导还原；R6G； 表面增强拉曼散射（SERS ）；SERS 活性基底 中图分类号：O657.37 Surface-Enhanced Raman Scattering Study on Silicon 20 Naniwire Arrays Decorated With Silver Nanoparticles SHI Meixia, DING Jianhua, WU Shifa (College of Physics and Optoelectronic Engineering, Dalian University of Technology, Liaoning 116024,China) Abstract: Silicon naniwires (SINWs) array were prepared by chemical wet etching and decorated 25 with a layer of TiO2 thin films , so the SERS substrate Ag/SINWs can be coated with silver nanoparticles under the condition of Uv irradiation .Based on the prepared substrate , the Raman spectroscopy of rhodamine 6G (R6G) can be obtained in low concentration as 10-9 M . The Raman mapping study show that the Ag/SINWs substrate has good enhancement ability and good uniformity . Detect the SERS of R6G with 10-7 M, during 1 to 30 days, the result indicate that the 30 Ag/SINWs substrate has good stability under the condition of room temperature .So the Ag/SINWs is a suitable SERS