赣南土壤中镉元素的激光诱导击穿光谱检测.pdfVIP

赣南土壤中镉元素的激光诱导击穿光谱检测 林永增 姚明印 陈添兵 刘木华 江西农业大学生物光电及应用实验室，南昌 330045 摘 要：将激光诱导击穿光谱技术(Laserinducedbreakdownspectroscopy，LIBS)用于检测赣南土壤中镉元素，对采自 赣南5个不同地区的土壤进行激光诱导击穿光谱试验，并在湿法消解后，用原子吸收分光光度计间接测出5种土壤中镉 元素的含量。根据Cd的特征光谱强度与其在土壤中的浓度关系，拟合出了线性拟合相关系数为0.9604的定标曲线，通 过定标曲线计算出镉元素的检测限为0.12μg/g，而国家标准土壤环境质量标准中镉的一级标准是≤0.20μg/g。因此，激 光诱导击穿光谱技术检测赣南土壤中重金属元素镉有很好的应用前景。 关键词：激光诱导击穿光谱技术；赣南土壤；镉元素；定标曲线 DetectionofCadmiuminGannanSoilUsingLaserInduced BreakdownSpectroscopy LinYongzengYaoMingyinChenTianbingLiuMuhua Optics-ElectricsApplicationofBiomaterialsLab, CollegeofEngineering,JiangxiAgriculturalUniversity, Nanchang330045,China Abstract: LaserinducedbreakdownspectroscopywasusedtodetectCadmiumelementinthesoilofGannan,hadanexperiment onthesoilcollectedfromfivedifferentregionsinGannan, andmeasuredtheconcentrationofcadmiuminthefivekindsofsoil indirectlybyatomicabsorptionspectrophotometerafterwetdigestion. Accordingtotherelationshipbetweenspectralintensityof cadmiumandtheconcentration,fitacalibrationcurvethatthelinearfittingcorrelationcoefficientis0.9604,thelimitsofdctec tionthatcanbecalculatedfromthecalibrationcurveis0.12μg/g,andtheconcentrationofcadmiuminthesoilthatdefinedin thesoilenvironmentqualitystandardofnationalstandardisunder0.20μg/g. So,itisaquitegoodapplicationprospecttode tectthecadmiumelementinthesoilofGannanbylaserinducedbreakdownspectroscopy. Keywords:Laserinducedbreakdownspectroscopy(LIBS) ; Gannansoil ; Cadmiumelement ; Calibrationcurv 迟发 生器DG535 搏激光脉冲。激： ！Hz，脉宽为8． 肛s，激光的工r 面应保持在同一一 ，巴琢）W工壤f ：．06nm处的特{ 用原子吸收分。 含量。通过浓廖 曲线，曲线拟毛 曲线计算得到C ～．Roshanzadeh nentpowderbyla iLasersinEngin, 姚明印，刘木华 中的Ba和SrE