1,22环己二醇溶解度的测定及关联.pdfVIP

第 55 卷 　第 9 期 化 　　　工 　　　学 　　　报 Vol55 　№9 ( ) 2004 年 9 月 Journal 　of 　Chemical 　Industry 　and 　Engineering 　 China September 　2004 化工数据 1 ,2环己二醇溶解度的测定及关联 周彩荣 　蒋登高 　王 　斐 ( ) 郑州大学化工学院, 河南 郑州 450002 摘 　要 　采用激光监视技术测定了 1 ,2环己二醇在乙酸甲酯、乙酸乙酯、乙酸丙酯、乙酸丁酯、丙烯酸甲酯、 丙烯酸乙酯、甲基丙基酮、乙酰乙酸乙酯和水中的溶解度 , 并用 UNIFAC 模型进行了关联 , 其溶解度预测值与实 测值吻合良好. 关键词 　1 ,2环己二醇 　溶解度 　激光检测技术 　UNIFAC 模型 中图分类号　O 6255 　　　　　文献标识码 　A 文章编号 　0438 - 1157 (2004) 09 - 1412 - 05 MEASUREMENT AND CORRELATION OF SOLUBILITIES OF 1 ,2CYCLOHEXANEDIOL ZHOU Cairong , J IANG Denggao and WANG Fei ( ) College of Chemical Engineering , Zhengzhou University , Zhengzhou 450002 , Henan , China Abstract 　By using laser monitoring technique , the solubilities of 1 ,2cyclohexanediol in different solvents , such as methyl acetate , ethyl acetate , propyl acetate , butyl acetate , methyl acrylate , ethyl acrylate , 2pentanone , ethyl acetoacetate and water , were measured in larger temperature intervals by the synthetic method. A solubility UNIFAC model was proposed. The model was verified with experimental data in ternary systems of both water + ethyl acetate + 1 ,2cyclohexanediol and water + butyl acetate + 1 ,2cyclohexanediol , and the solubilities were calculated by the model and agreed with experimental