【高分子材料与工程】【毕业设计+开题报告+文献综述】聚丙烯聚丙烯碳纳米管复合材料的光稳定性研究.doc

（20届） 毕业设计 摘要： 关键词：  Abstract：ulti-wall carbon nanotubes (MW-CNTs) were melt compounded with polypropylene (PP) in order to assess their effect on the photo-oxidation behaviour of the resultant PP/MW-CNTs composites. The mechanical properties of PP/MW-CNTs composites with various MW-CNTs were tested before and after photo-oxidation. Results showed that before photo-oxidation, the tensile strengths of the samples increased with the increase of MW-CNTs contents when the MW-CNTs contents were less than 1% wt, whilst the tensile strength decreased at higher MW-CNTs contents (1% wt). When subjected to photo-oxidation, the tensile strengths of the samples decreased with the increasing photo-oxidation time. The resistance to accelerated photo-oxidation of PP/MW-CNTs composites was also compared with the photo-oxidation behaviour of the original polypropylene sample. At short photo-oxidation time, such as under 250 h, the rates of carbonyl formation for the PP/MW-CNTs composites are similar to that observed for the original polypropylene but at longer photo-oxidation times the carbonyl formation increases for lower MW-CNTs contents (0.1, 0.2, 0.5 and 0.8% wt), and decreases for higher MW-CNTs contents (1 and 2% wt). It was found that the MW-CNTs showed both anti-degradation and pro-degradation effects at different concentrations. Keywords: Polypropylene; Carbon nanotube; Mechanical properties; Photo-oxidation 目录 摘要 VI Abstract.....................................................................................................................................................V 1 绪 论 1 1.1 聚丙烯材料 1 1.1.1 聚丙烯生产工艺介绍 1 1.1.2 聚丙烯的改性 1 1.2 碳纳米管的结构、性能及制备 2 1.2.1 碳纳米管结构和性能 2 1.2.2 碳纳米管的制备 2 1.3 聚丙烯/碳纳米管复合材料 3 1.4 碳纳米管/聚合物复合材料的性能 4 1.4.1 力学性能 4 1.4.2 光学性能 5 1.4.3 电性能 5 1.4.4 助燃性与耐热性 5 1.5 碳纳米管在聚丙烯复合材料的发展现状 5 2 实验部分 7 2.1 实验原料 7 2.2 实验设备 7 2.3 试样制备 7 3 结果与分析 8 3.1 材料的力学性能测试 8 3.2 材料的光氧化行为研究 8 3.3 材料的形貌分析 11 4 总结与展望 13 参考文献 14 致 谢 16 绪 论 1.1 聚丙烯材料 聚丙烯(PP)作为一种通用塑料