聚醚砜磺化工艺的研究.pdfVIP

聚醚砜磺化工艺的研究 翟丁，周勇，高从堦 (杭州水处理技术研究开发中心，浙江， 杭州 310012) 摘要：以二氯甲烷为溶剂，以二氯甲烷为溶剂，氯磺酸为磺化剂对聚醚砜（PES）进行磺化 改性，制备了不同磺化度的磺化聚醚砜（SPES ），对磺化时间和磺化剂用量进行了探讨， 结果表明：在较低温度、较短的反应时间内反应时，可以通过改变磺化剂的用量可以对磺化 度进行控制；随聚醚砜的磺化度增加，其水溶性增强。 关键字：聚醚砜 磺化 氯磺酸 中图分类号：TQ326.65 The synthesis and characterization of hydrophilic Sulfonated Polyether sulfone ZHAI Ding, ZHOU Yong, GAO Congjie The Development Center of Water Treatment Technology,Hangzhou,310012 Abstract: In this paper the polyethersulfone was modified by sulfonation with chlorosulfonic acid as sulfonation agent and Dichloromethane as solvent.Sulfonated PES(SPES)with different degrees of sulfonation were prepared.Factors affecting the sulfonation reaction such as the sulfonation time and the mole ratio of chlorosulfonic acid and PES were studied and and sulfonated products were characterized. the results demonstrated that reaction system wasn’t uniform after a session of sulfonation;the degree of sulfonation can be controlled through the change of amount of sulfonation agents when reacted in a low temperature and short time;the degree of sulfonation of PES increased,the hydrophilicity increased Key words: polyethersulfone ；sulfonation；chlorosulfonic acid 基金项目：国家重点基础研究发展规划（973）项目(2009CB623402)；国家高科技研究发展计划（863）项 目(2007AA030302)；国家高科技研究发展计划（863）项目（2009AA032201）；钱江人才计划（2009R10067） 作者简介：翟丁（1982- ），男，河北人，工程师，研究方向为高分子膜材料：xinmor@163.com [1] 聚醚砜是一种性能优异的特种工程塑料 ，可以应用于非常多的过程，比如反渗透膜、超滤膜、离子 交换膜以及类似的过程中[2] 。但亲水性能差，在制作膜材料时，透水速率低而直接影响其分离功能及应用， 需要磺化改性,其磺化过程如图1. O SO2 + CLSO H O SO2 + HCl 3 n n