金属卟啉类仿生催化剂的合成_构效关系及在催化氧化碳氢化合物中的应用.pdfVIP

226 精 细 化 工 Vo.l 22, No. 6 2 00 5 6 FINE CHEM ICALS June 2 0 0 5 * 佘远斌, 王兰芝, 宋旭锋, 张燕慧, 陈一霞 ( , 100022) : () , ( 80~ 140 e , 01 5~ 01 8M Pa 2 h), 2003, , 8% ~ 10% , 90% , 57 : ; ; ; : Q426. 8 : A : 1003- 5214( 2005) 06- 0401- 08 SynthesisandQSAR ofM etalPorphyrin BiomimeticCatalysts and TheirApplication in xidation ofHydrocarbons SHE Yuan-bin, WANG Lan-zh,i SONG Xu-feng, ZHANG Y an-hu,i CHEN Y i-xia (Institu te of G reen Chem istry, D ep artm ent of Chem istry and Chem ical E ng ineering, B e ij ing Univ ersity of Technology, B e ij ing 100022, Ch ina ) Abstract:Research progress on the theoretical background, synthesis and QSAR of m etal porphyrin biom mi etic catalysts and their application in green synthesis of organic intermediates and products by oxidation of hydrocarbons are reviewed. he research achievem ents on metal porphyrin biom mi etic catalysis of our group and professor Guo Canchengc group in recent years are systematically and emphatically reported, including design, synthesis and QSAR of m etal porphyrin and metal phthalocyanine biom mi etic catalysts and their application in green synthesis of o, m, p-nitrobenzoic acids, o, p-nitro-benaldehydes, adipic acid, cyclohexanone, cyclohexanol, dihydroxybenzenes etc. by catalytic oxidation of o, m, p-nitrotoluenes, cyclohexane, phenol and other hydrocarbons. he most mi portm ent achievement was that the novel technology of catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanolw ith L-oxo-bisironporphyrin compounds asbiom mi etic catalysts and air