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Impedance spectroscopy study of high-temperature oxidation of
Gd O -Yb O codoped zirconia thermal barrier coatings
2 3 2 3
ZHANG Dan-hua, GUO Hong-bo, GONG Sheng-kai
School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics,
Beijing 100191, China
Received 18 October 2010; accepted 6 December 2010
Abstract: 3Gd O -3Yb O -4Y O (mole fraction, %) co-doped ZrO (GY-YSZ) thermal barrier coatings (TBCs) were produced by
2 3 2 3 2 3 2
electron beam physical vapor deposition (EB-PVD). The oxidation behavior of GY-YSZ at 1 050 °C was investigated using
impedance spectroscopy (IS) combined with scanning electron microscopy (SEM), Raman spectroscopy and X-ray diffractometry
(XRD). Various electrical responses observed in the impedance spectra corresponding to GY-YSZ grains and grain boundaries were
2−
explained using circuit modeling. The change in the conduction mechanism of GY-YSZ was found to be related to the O vacancy
and lattice distortion due to the stabilizer diffusion during the oxidation. The results also suggested that the specific oxidation
information about the GY-YSZ grains and grain boundaries should be acquired at a moderate measurement temperature, which was
related to the resistance value in the impedance spectra. The resistance values of the GY-YSZ grains and grain boundaries should be
measured at 200 °C and 300 °C, respectively.
Key words: rare earth oxide; Gd O
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