甲醇氨氯化法反应催化剂的研究.pdfVIP

甲醇氨氯化法反应催化剂的研究 孙玉捧，刘硕，尚建楠，刘玉敏，胡永琪 （河北科技大学化学与制药工程学院，河北石家庄 050018） 摘要：利用等体积浸渍法制备催化剂，并在催化剂作用下，甲醇和氯化铵反应生产氯甲烷和氨，氨可以作为原料循 环使用于生产纯碱，氯甲烷是合成甲基氯硅烷的基础原料，具有较高的附加值。采用固定床反应器，首先进行催化 剂的筛选，并对筛选后效果好的催化剂的制备工艺条件进行改进，探索对催化生成氯甲烷收率高的催化剂，并采用 气相色谱分析仪对产物进行分析和检测。结果表明，以γ-Al O 、高岭土、HZSM-5 为载体，负载4%Co(NO ) 金 2 3 3 2 属活性组分的催化剂条件下，氯化铵和甲醇原料比为1 ∶1.1，反应温度在330℃～390℃，适宜空速为0.7s-1 时，效 果最佳，甲醇的转化率达到90% 以上，氯甲烷收率可达到73.25% 。 关键词：纯碱；氯化铵；氯甲烷；催化剂；收率； 中图分类号：TQ032.4 文献标识码：A The catalyst of the reaction of methanol and ammonia chloride Sun Yupeng, Liu Shuo, Shang Jiannan,Liu Yumin,Hu Yongqi （Chemical and Pharmaceutical Engineering，Hebei University of science and Technology ， Shijiazhuang,050018, Hebei,China ） Abstract ：With the presence of a catalyst prepared by impregnation method,a new process to react ammonium chloride with methanol was proposed in this thesis to produce chloromethane and ammonia. Ammonia can be recycled as raw materials in the production of soda ash, chloromethane is the basic raw materials for synthesis of methyl chloride silane, moreover chloromethane has high added value.This thesis uses the fixed bed reactor, the catalyst was the first screening, and screening effects good catalyst preparation conditions to improve, explore catalytic generated a catalyst for high yield of methyl chloride, using gas chromatography analyzer products were analysis and testing.The results showed that the best conditions are: the best the catalyst with γ-Al O , kaolin, HZSM-5 as the carrier, the load 4% Co (NO ) 2 3 3 2 metal under the conditions of the active component of th