聚乳酸纤维染色工艺优化与研究.pdfVIP

聚乳酸纤维染色工艺的优化研究 1 2 2 郭申 曾丽平 曹丽云 1.富维薄膜（山东）有限公司，山东潍坊（261061） 2.陕西科技大学材料科学与工程学院，西安（710021） 摘要：通过研究发现，分散染料(以分散红 74 加入量为 1% owf 为例)对聚乳酸纤维的 染色条件为：染色温度 105℃、染色时间 30min、浴比 1:30、PH=4-5、阴离子表面活 性剂 JS-N 为 1.0g/L、匀染剂 2011 1.0g/L。在 75-95℃的染色范围内，上染百分率对 温度比较敏感，随温度的上升，上染百分率显著增加。在 75℃以下，几乎不上染；在 95℃以上，上染百分率随染色时间的增加不是很敏感，上染百分率增加比较缓慢。另 外，对染色前后纤维的形貌进行了观察，发现染色后纤维横截面产生了许多分布不均 的微孔结构。 关键词：聚乳酸纤维，优化，正交试验，提升性，助剂 Optimization of dyeing process of PLA fibers 1 2 2 GUO Shen , Zeng Li-Ping , Cao Li-yun (1. FuWei Films Co. Ltd, Weifang, Shandong, P.R .China, 261061) (2. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi, P.R. China, 710021) Abstract : The dyeing behaviors of PLA fiber with disperse dyes with two different chemical structure were studyed. PLA fiber dyeing conditions were: dyeing temperature 105℃, dyeing time 30 min, dyeing bath 1:30, PH = 4～5, anionic surfactants JS-N1.0 g/L, leveler 2011 1.0g/L (for example disperse Red 74, the addition of 1% owf ). In the dyeing temperature(T) of 75～95 ℃ , the percentage of are very sensitive to T. As the temperature added, the exhaustion percentage increased significantly. Below 75 ℃or above 95 ℃, the exhaustion was not obvious.In addition, morphology and structure of PLA fibers before and after dyeing were observed by scanning electronic microscope (SEM), a lot of uneven distribution porous structure appeared in the cross section. Keywords : PLA fiber, optimize, Orthogonal test , build up, dyeing auxiliaries 聚乳酸(PLA) 纤维是二十一世纪最具有竞争力的脂肪族聚酯纤维，具有很好的 生物可降解性和生物相容性[1] 。聚乳酸（PLA）纤维亦称玉米纤维，受到纺织、化工 和消费者的广泛关注[2-3]，