催化燃烧Cl-VOCs催化材料研究进展.pdfVIP

Material Sciences 材料科学, 2011, 1, 10-16 doi:10.4236/ms.2011.11003 Published Online April 2011 (/journal/ms/) Recent Progress in Catalytic Materials for Catalytic Combustion of Chlorinated Volatile Organic Compounds# 1 1* 2 Xuehua Yang , Aidong Tang , Xianwei Li 1School of Chemistry and Chemical Engineering, Central South University, Changsha 2Institute of Environment and Resource, Baosteel Co., Ltd., Shanghai Email:tangaidong@126.com Received: Mar. 14th, 2011; revised: Apr. 15th, 2011; accepted: Apr. 20th, 2011. Abstract: The research progress in the catalytic combustion of Cl-VOCs(Chlorinated Volatile Organic Compounds) is reviewed. In this review, the effects of the active species, catalyst support, water vapor and coking on the catalytic combustion reaction were summarized. The research related to noble metal catalysts mainly focuses on developing new supports and dual noble catalysts. The research on non-noble metal cata- lysts concentrate on the development of transition metal mixed oxide, perovskites and spinel catalysts; The chlorination of active species is regarded as an important reason for catalyst deactivation. Besides, the effects of water vapor and coking deactivation on the catalytic combustion process are discussed with considering the practical application. This review will be helpful in choosing an appropriate catalyst and the optimal reac- tion conditions for the removal of Cl-VOCs by catalytic combustion with high activity and high stability. Keywords: Catalyst; Noble metal; Metal oxide; Chlorinated Volatile Organic Compounds; Deactivation