PVB%2fNi导电功能梯度材料研究的论文.pdfVIP

PVB/Ni导电功能梯度材料研究 刘 鹏 温变英*方晓霞 宦春花 北京工商大学 材料与机械工程学院，北京，100048 目前，电磁辐射污染已呈现越来越严重之势，采用屏蔽材料对电磁波进行屏蔽，是减轻电 磁辐射污染的有效途径之一。将导电复合材料梯度化是解决均质电磁波屏蔽材料中力学性能与 电磁波屏蔽性能不能兼顾的有效方法[1]。本文以Stokes法则为理论依据，采用重力沉降法，成 功地制备了系列导电粒子的聚合物基体中呈梯度分布的功能膜材料[2]，并与同组分均质导电复 合材料的性能进行了对比。 关键词：梯度功能材料;流延;导电;聚乙烯醇缩丁醛;镍粉 StudyonPVB/NiConductiveFunctionallyGradientMaterials LIUPengWENBianvingFANGXiaoxiaHUAN Chunhua SchoolofMaterialsandMechanicalEngineering,BeijingTechnologyandBusinessUniversity, Beijing100048 Abstract:Recentyears,electromagneticradiationpollutionbecomesmoreandmoreserious,sothe developingelectromagneticshieldingmaterialsareimperative.However,thereisanirreconcilable contradictionbetweentheelectricallyconductiveperformanceandmechanicalpropertyina homogeneousconductivecomposite.Inthispaper,theconceptofFunctionalgradientmaterialsis introducedtopreparepolymericgradientelectricallyconductivecomposites.AccordingtoStokes law,aseriesofPVB/Nigradientelectricallyconductivecompositeswerepreparedbyuseof suspendedcastingmethod.Electricallyconductivetestsshowthatthepercolationthreshhold occurredat4.5vol％ onfillerrichsideofthePVB/Nigradientfilm,whichismuchlowerthanthat ofhomogeneouselectricallyconductivecomposites;Besides,Thetensilestrengthofthegradient filmisnolowerthanthatofneatPVBresin,Thisisbecausethegradientdistributionoffiller guaranteematerialsmechanicalperformance;incontrast,thetensilestrengthofthehomogeneous filmdecreasedwiththeincreaseofthefillercontentduetotheaggregationoffillers.Experiments demonstratethatsuspensioncastingisaneffectivemethodtopreparefilledpolymericgradient composites. Keywords:Functionalgradientmaterials; Suspendedcasting; conductive; PVB;Ni