微型反应器中甲醇水蒸汽重整制氢的研究.pdfVIP

微型反应器中甲醇水蒸汽重整制氢研究 王锋，漆波，邓联锋，李隆键，崔文智，辛明道，陈清华 （重庆大学动力工程学院，400030，重庆） 摘 要：为了强化甲醇水蒸气重整制氢过程，研制了一种集燃料预热、汽化、过热和重整反应功能于一体的微型 反应器。实验考察了反应温度、水醇比、液体空速等对甲醇转化率、产氢率、反应器出口氢气和一氧化碳浓度的 影响，建立了该反应器的数学和动力学模型并进行了三维数值模拟。结果表明，模型能较好的反映出反应器的性 能；当反应温度、水醇比和液体空速分别为 260 ℃、1.3、0.15 h-1 时，产氢率达 0.15 mol/(hgcat) ，能为氢气利用率 为 80%、效率为 60%的燃料电池提供 10.2W 的功率。 关键词：甲醇水蒸气重整；制氢；微型反应器 中图分类号：TK16 文献标识码：A Methanol Steam Reforming for Hydrogen Production in a Minireactor Wang Feng, Qi bo, Deng Lian-feng, Li Long-jian, Cui Wen-zhi, Xin Ming-dao, Chen Qing-hua (College of Power Engineering, Chongqing University, Chongqing, 400030, China) Abstract ：In order to intensity the process of methanol steam reforming for hydrogen production, a minireactor which consists the preheat、evaperation、superheat of liquid methanol and water and reaction section is designed and fabricated. The effects of reaction temperature、water and methanol molar ratio 、liquid space velocity on the reactor outlet parameters such as methanol conversion are studied through experiment. The 3-D model is established for the reactor and the simulation results can describe the performance of the reactor. Results show that when the reaction temperature is 260℃、methanol molar ratio is 1.3、liquid space velocity is 0.15 h-1, the yield of hydrogen reaches 0.15 mol/(hgcat), this can provide the hydrogen for 10.2W fuel cell with the hydrogen utilisition efficiency of 80% and cell efficiency of 60%. Keywords ：methanol steam reforming; hydrogen production; minireactor 质子交换膜燃料电池(PEMFC)是公认的 21 世 外，将加热方式改为微波直接加热[7] 、通过光催化 [8] [9] 纪高效、节能、环保的发电方式，在固定电站和移 甲醇制氢 、采用膜分离技术 等也是有效的强化 动电源方面有着广泛的应用前景，但要实现商业化 手段。尤其是近年来采用微化工技术进行甲醇蒸气 必须解决其氢源问题