MSF屏蔽技术_电感耦合等离子体原子发射光谱法测定高温合金中微量Mg.pdfVIP

第 14 卷 　总第 57 期 特钢技术 Vol . 14 (57) 2008 年第 4 期 Special Steel Technology 2008 ,No . 4 理化检测与计控 MSF 屏蔽技术 ─电感耦合等离子体原子发射 光谱法测定高温合金中微量 Mg 吴世凯 (攀长钢公司计量检测中心 ,四川江油 621704) 　　摘 　要 :采用 ICP - AES 法对铁 、镍基高温合金中微量 Mg 元素的测定进行了研究 ,着重考察高温合金中基体与 合金元素对 Mg 含量测定的影响 ;应用 MSF 及屏蔽技术进行干扰消除研究 ,通过优选试样溶解方式 、最佳分析谱线及 用 BEC 确定仪器工作参数 ,对准确度和精密度进行检验 ,本方法简单 、快速 、准确 、可靠 。 关键词 :ICP - AES ;高温合金 ;MSF 屏蔽技术 ;Mg 。 + ( ) 中图分类号 :TG115. 3 　　文献标识码 :A 　　文章编号 :1674 - 0971 2008 04 - 028 - 03 Determination of Trace Mg in High Temperature Alloy by ICP - AES with MSF Wu 　Shikai ( Metering and Measuring Center , Sichuan Changcheng Special Steel Co . ,Ltd . , Pangang Group , Jiangyou 621704) 　　Abstract :This paper studied the determination of trace element Mg in iron —base and nickel - base high temperature alloy by ICP - AES , focused on the effect of the matrix and alloy elements in high temperature alloy on determination of Mg contents , inter ference elimination study was carried out by method of MSF and shielding technology , the accuracy and precision of this method were tested by optimizing dissolution way of sample and the best analytical spectral lines and determining the operation parameters of the instrument using BEC. It was concluded that this method was simple , rapid , accurate and reliable . Key Words :ICP - AES , High temperature alloy , MSF ,Mg. 　　高温合金是具有 良好的力学性能和综合的强 、 韧性指标 , 具有较高的抗腐蚀性能的一类合金 ,