XPS研究Ti32Mo在浓盐酸溶液中钝化膜结构.pdfVIP

第 15 卷 第 3 期 腐蚀科学与防护技术 Vol 15 No3 2003 年 5 月 　　　　 　　　　 May2003 CORROSION SCIENCE AND PROTECTION TECHNOLOGY XPS 研究 Ti32Mo 在浓盐酸溶液中钝化膜结构 屈定荣 　武显亮　王光耀 北京化工大学材料科学与工程学院 100029 摘要 　用 XPS 研究了 Ti32Mo 在 70 ℃、4 mol/ L 盐酸溶液阳极电位为 0 2 V 和 0 9 V 时的钝化膜结构和组成. 结果 表明 ,钝化膜是由表层和过渡层组成的双层结构. 对于阳极电位为 0 2 V 的试样 ,钝化膜富集因子 f (Mo) 随溅射深 度增加 , 由最外层的175 变化到 8 nm 时的 140 ;而对于阳极电位为 0 9 V 的试样 ,钝化膜富集因子f (Mo) 在 132 ～142 之间变化. 钝化膜的表层可成 Ⅰ和 Ⅱ两个亚层 ,其组成主要是 Ti 和 Mo 不同价态的氧化物、氢氧化物和氯 化物. 关键词 　钝化膜 　XPS 　Ti 　Mo 中图分类号 　TG113. 2 　　文献标识码 　A 　　文章编号 (2003) XPS STUDIES ON PASSIVE FILMS FORMED ON Ti32Mo ALLOY IN HCl SOL UTION QU Dingrong ,WU Xianliang ,WAN G Guangyao College of M aterial Science and Engineering , Beijin g U niversity of Chemical Technology , Beijin g 100029 ABSTRACT 　The composition and structure of passive films formed on Ti32Mo at different anodic po larization potentials (0. 2V and 0. 9V (vs. SCE) ) in 70 ℃、4 mol/ L HCl solution have been studied by XPS. It was found that the passive films were composed of an outer layer and an inner layer. The en richment factor of Mo on the outermost layer for the sample formed at 0. 2V is 1. 75 ,and the then de crease to 140 at a depth 8 nm. The enrichment factor of Mo f (Mo) for the sample formed at 0. 9V is varied between 1. 32～1. 42. The outer layer can be divided into two sub - layers. The passive films are consisted of a titanium - molybdenum compound containing oxide ,hydroxide and chloride. KEY WORDS 　passive film ,XPS , Ti ,Mo 　　Ti - Mo 合金在热的浓盐酸、中等浓度硫酸和 面 , 以保护试样圆柱面和接线口. 用水砂纸打磨