多频超声反应槽连续强化酸化油酯交换制备生物柴油研究.pdfVIP

第42卷 第8期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.8 2014年8月 Journal of Fuel Chemistry and Technology Aug. 2014 文章编号:0253鄄2409(2014)08鄄0973鄄05 多频超声反应槽连续强化酸化油酯交换制备生物柴油研究 邹华生,李雪峰,熊乔兴 (华南理工大学 化学与化工学院,广东 广州摇 510640) 摘摇 要:以平均酸值高达33.07mgKOH/ g不可食用的廉价酸化油为原料,利用自行设计的多频超声溢流槽连续强化酯交换 反应生物柴油生产装置,先后经预酯化、酯交换两步反应,高效、低耗的制备生物柴油。 主要考察了室温下物料流量(停留时 间)、超声功率、超声频率及组合、KOH用量、醇油物质的量比对酯交换反应的影响及单位产品能耗。 结果表明,多频组合超声 辐射比单频更有利于生物柴油的制备;预酯化后的油料在流量为25 L/ h(物料停留时间为54 min),催化剂(KOH)用量为 1.2%(质量分数),醇油物质的量比为6颐1和各反应槽功率为200W 的条件下,甲酯产率达96.83%。 50L废弃酸化油能制得 符合国标GB19147—2009 的生物柴油48L,整个生物柴油制备过程总耗时和总耗电量仅为8.667h、5.42kWh。 关键词:酸化油;生物柴油;多频超声;连续式 中图分类号:TQ645.1摇 摇 文献标识码:A Preparation of biodiesel via continuous transesterification in multi鄄frequency ultrasonic reaction tank ZOU Hua鄄sheng,LI Xue鄄feng,XIONG Qiao鄄xing (School of Chemistry and ChemicalEngineering,South China University of Technology,Guangzhou摇 510640,China) Abstract:The preparation of biodiesel from inedible low鄄cost acid oil with a high average acid value(AV) of about 33. 07 mgKOH/ g via pre鄄esterification and transesterification processes in a self鄄designed continuous biodiesel production apparatus assisted by multi鄄frequency ultrasonic at high efficiency and low energy consumption was investigated. The influences of operating variables including flow rate of material(residence time),ultrasonic power and frequency or combinations,the amount of catalyst,the molar ratio of methanol to oil at ambient temperatureandthe specificenergy consumption onthetransesterificationreaction werediscussed. The results show that multi鄄frequency ultrasonic irradiation is superior to single鄄frequency in enhancing biodiesel productionprocess;theyieldoffattyacidmethylesters(FAME)about96.83% isattainedwith 15鄄25鄄35鄄40kHz of frequ