天然酚酸类化合物对生物柴油氧化安定性的影响.pdfVIP

2014年第39卷第12期　 　 　 　 　 　 　 　 　 　 　 　 　 中　 国　 油　 脂 61 生物柴油 天然酚酸类化合物对生物柴油氧化安定性的影响 吴　 婧,王　 忠,毛功平,胡慧慧,王燕鹏 (江苏大学汽车与交通工程学院,江苏镇江212000) 摘要:探讨了天然酚酸类化合物对抑制生物柴油氧化反应的影响,并分析了天然酚酸类化合物及 BHT对生物柴油的酸值和过氧化值的影响。 研究结果表明:天然酚酸类化合物可有效降低生物柴 油的酸值和过氧化值。 其中,迷迭香提取物的抗氧化效果最好,添加0.10%迷迭香提取物样品, 360 h 时酸值降低46.6%,过氧化值降低38.9%。 添加0.04% BHT样品在相同条件下的酸值和过 氧化值均高于添加0.04%迷迭香提取物样品的。 迷迭香提取物中的强弱抗氧化成分之间形成协 同作用,提高抗氧化效果;并且猝灭单重态氧,抑制生物柴油的光氧化。 关键词:酚酸类化合物;生物柴油;酸值;过氧化值 中图分类号:TK63;TS202.3　 　 文献标志码:A　 　 文章编号:1003-7969(2014)12-0061-04 Impact of natural phenolic acids compound on oxidative stability of biodiesel WU Jing ,WANG Zhong,MAO Gongping,HU Huihui,WANG Yanpeng (School of Automobile and Traffic Engineering,Jiangsu University,Zhenjiang212000,Jiangsu,China) Abstract:Theinhibitoryeffectofnaturalphenolicacidscompoundontheoxidationofbiodieselwasdiscussed, and the effectsof naturalphenolicacidscompoundandBHTontheacidvalueandperoxidevalueof biodiesel were analyzed.The results showedthat the natural phenolic acids compound could reduce the acid value and peroxide value of biodiesel effectively. Among them,the antioxidant effect of rosemary extract was the best, andthe acid value and peroxide value of biodiesel reduced by 46.6% and 38.9% respectively after 360 h when0.10% rosemary extract wasaddedto biodiesel. The acid value and peroxide value of biodiesel added with0.04% BHTwere both higher than that added with0.04% rosemary extract under the same condition. The synergistic action between strong and weak antioxidant components in rosemary extract improved the an- tioxidant effect andthe rosemary extract preventedbiodieselfromphotooxidationby quenching single oxygen. Key words:phenolic acids compound;biodiesel;acid value;peroxide value